| 题名 | Nickel-Catalyzed Highly Enantioselective Hydrogenation of beta-Acetylamino Vinylsulfones: Access to Chiral beta-Amido Sulfones |
| 作者 | |
| 通讯作者 | Lv, Hui; Zhang, Xumu |
| 发表日期 | 2018-09-21
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| DOI | |
| 发表期刊 | |
| ISSN | 1523-7060
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| EISSN | 1523-7052
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| 卷号 | 20期号:18页码:5914-5917 |
| 摘要 | The nickel/(S)-Binapine complex was found to be an efficient catalyst for asymmetric hydrogenation of beta-acetylamino vinylsulfones to afford chiral beta-Amido sulfones with excellent yields and enantioselectivities (up to 95% yields and >99% ee). This protocol has good compatibility with a series of substituted (Z)-beta-acetylamino vinylsulfones or Z/E isomeric mixtures. A gram-scale reaction has also been achieved in the presence of a 0.2 mol % catalyst loading. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
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| 重要成果 | NI期刊
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| 学校署名 | 通讯
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| 资助项目 | Important Sci-Tech Innovative Project of Hubei Province[2015ACA058]
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| WOS研究方向 | Chemistry
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| WOS类目 | Chemistry, Organic
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| WOS记录号 | WOS:000445711500086
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| 出版者 | |
| ESI学科分类 | CHEMISTRY
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| 来源库 | Web of Science
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| 引用统计 |
被引频次[WOS]：59
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| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/27219 |
| 专题 | 理学院_化学系 深圳格拉布斯研究院 |
| 作者单位 | 1.Wuhan Univ, Key Lab Biomed Polymers, Minist Educ, Wuhan 430072, Hubei, Peoples R China 2.Wuhan Univ, Coll Chem & Mol Sci, Engn Res Ctr Organosilicon Cpds & Mat, Minist Educ, Wuhan 430072, Hubei, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China 4.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 通讯作者单位 | 化学系; 深圳格拉布斯研究院 |
| 推荐引用方式 GB/T 7714 |
Long, Jiao,Gao, Wenchao,Guan, Yuqing,et al. Nickel-Catalyzed Highly Enantioselective Hydrogenation of beta-Acetylamino Vinylsulfones: Access to Chiral beta-Amido Sulfones[J]. ORGANIC LETTERS,2018,20(18):5914-5917.
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| APA |
Long, Jiao,Gao, Wenchao,Guan, Yuqing,Lv, Hui,&Zhang, Xumu.(2018).Nickel-Catalyzed Highly Enantioselective Hydrogenation of beta-Acetylamino Vinylsulfones: Access to Chiral beta-Amido Sulfones.ORGANIC LETTERS,20(18),5914-5917.
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| MLA |
Long, Jiao,et al."Nickel-Catalyzed Highly Enantioselective Hydrogenation of beta-Acetylamino Vinylsulfones: Access to Chiral beta-Amido Sulfones".ORGANIC LETTERS 20.18(2018):5914-5917.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| acs.orglett.8b02579.（1475KB） | -- | -- | 限制开放 | -- | ||
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