| 题名 | Dynamical resonances in chemical reactions |
| 作者 | |
| 通讯作者 | Xiao, Chunlei; Sun, Zhigang; Zhang, Donghui; Yang, Xueming; Weichman, Marissa L.; Neumark, Daniel M. |
| 发表日期 | 2018-09-07
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| DOI | |
| 发表期刊 | |
| ISSN | 0306-0012
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| EISSN | 1460-4744
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| 卷号 | 47期号:17页码:6744-6763 |
| 摘要 | The transition state is a key concept in the field of chemistry and is important in the study of chemical kinetics and reaction dynamics. Chemical reactions in the gas phase are essentially molecular scattering processes, which are quantum mechanical in nature. Thus probing and understanding detailed quantum structure in the transition state region of chemical reactions, such as reactive resonances, is a central topic in this field. In this article, we focus on recent progress in the study of resonances in elementary bimolecular reactions using state-of-the-art transition state spectroscopy methods: high-resolution photoelectron spectroscopy and quantum state specific backward scattering spectroscopy. The experimental results are compared with high-level quantum dynamics calculations based on highly accurate potential energy surfaces. The dynamics of reactive resonances are also interpreted based on scattering wavefunctions obtained by time-dependent wavepacket calculations. Here, we review many systems that illustrate how reactive resonances can strongly influence the dynamics of elementary chemical reactions. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
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| 学校署名 | 通讯
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| 资助项目 | Air Force Office of Scientific Research (AFOSR)[FA9550-12-1-0160]
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| WOS研究方向 | Chemistry
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| WOS类目 | Chemistry, Multidisciplinary
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| WOS记录号 | WOS:000443171000003
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| 出版者 | |
| ESI学科分类 | CHEMISTRY
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| 来源库 | Web of Science
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| 引用统计 |
被引频次[WOS]：36
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| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/27250 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, 1088 Xueyuan Rd, Shenzhen 518055, Peoples R China 3.Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA 4.Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA 5.NIST, JILA, Boulder, CO 80305 USA |
| 通讯作者单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Wang, Tao,Yang, Tiangang,Xiao, Chunlei,et al. Dynamical resonances in chemical reactions[J]. CHEMICAL SOCIETY REVIEWS,2018,47(17):6744-6763.
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| APA |
Wang, Tao.,Yang, Tiangang.,Xiao, Chunlei.,Sun, Zhigang.,Zhang, Donghui.,...&Neumark, Daniel M..(2018).Dynamical resonances in chemical reactions.CHEMICAL SOCIETY REVIEWS,47(17),6744-6763.
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| MLA |
Wang, Tao,et al."Dynamical resonances in chemical reactions".CHEMICAL SOCIETY REVIEWS 47.17(2018):6744-6763.
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| 条目包含的文件 | 条目无相关文件。 | |||||
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