南方科技大学知识苑(SUSTech KC): Scope and Mechanism on Iridium-f-Amphamide Catalyzed Asymmetric Hydrogenation of Ketones

题名	Scope and Mechanism on Iridium-f-Amphamide Catalyzed Asymmetric Hydrogenation of Ketones
作者	Liang, Zhiqin1 ; Yang, Tilong 1; Gu, Guoxian 1; Dang, Li1,2,3 ; Zhang, Xumu1
通讯作者	Dang, Li; Zhang, Xumu
发表日期	2018-09
DOI	10.1002/cjoc.201800129
发表期刊	CHINESE JOURNAL OF CHEMISTRY 影响因子和分区
ISSN	1001-604X
EISSN	1614-7065
卷号	36 期号:9页码:851-856
摘要	A series of novel and easily accessed ferrocene-based amino-phosphine-sulfonamide (f-Amphamide) ligands have been developed and applied in Ir-catalyzed asymmetric hydrogenation of aryl ketones, affording the corresponding chiral secondary alcohols with excellent results (up to >99% conversion, >99% ee and TON up to 200 000). DFT calculations suggest an activating model involving an alkali cation Li+.
关键词	aryl ketone asymmetric f-Amphamide hydrogenation iridium
相关链接	[来源记录]
收录类别	SCI ; IC
语种	英语
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China[21573102]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000441435300010
出版者	WILEY-V C H VERLAG GMBH
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：48
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/27291
专题	理学院_化学系
作者单位	1.Southern Univ Sci & Technol, Dept Chem, 1088 Xueyuan Rd, Shenzhen 518055, Guangdong, Peoples R China 2.Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China 3.Shantou Univ, Key Lab Preparat & Applicat Ordered Struct Mat Gu, Shantou 515063, Guangdong, Peoples R China
第一作者单位	化学系
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Liang, Zhiqin,Yang, Tilong,Gu, Guoxian,et al. Scope and Mechanism on Iridium-f-Amphamide Catalyzed Asymmetric Hydrogenation of Ketones[J]. CHINESE JOURNAL OF CHEMISTRY,2018,36(9):851-856.
APA	Liang, Zhiqin,Yang, Tilong,Gu, Guoxian,Dang, Li,&Zhang, Xumu.(2018).Scope and Mechanism on Iridium-f-Amphamide Catalyzed Asymmetric Hydrogenation of Ketones.CHINESE JOURNAL OF CHEMISTRY,36(9),851-856.
MLA	Liang, Zhiqin,et al."Scope and Mechanism on Iridium-f-Amphamide Catalyzed Asymmetric Hydrogenation of Ketones".CHINESE JOURNAL OF CHEMISTRY 36.9(2018):851-856.