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题名

Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties

作者
通讯作者Liu, Hongyang; Zou, Xiaoxin
共同第一作者Li, Zhenyu; Zhao, Linmin
发表日期
2022
DOI
发表期刊
ISSN
2044-4753
EISSN
2044-4761
卷号12页码:1038-1042
摘要

Three crystal phases of Pd-B intermetallics, namely, Pd6B, Pd5B2 and Pd2B, are synthesized, and their phase-dependent catalytic activities toward electrochemical water splitting and Suzuki coupling reactions are studied. In both reactions, their catalytic activities are found to increase in the order Pd, Pd6B, Pd5B2 and Pd2B. This activity trend is strongly associated with the Pd(d)-B(s,p) orbital hybridization-regulated surface adsorption properties.

相关链接[来源记录]
收录类别
SCI ; EI
语种
英语
学校署名
其他
资助项目
National Natural Science Foundation of China (NSFC)[21922507,21771079,21901083,22179046] ; Fok Ying Tung Education Foundation[161011] ; Fundamental Research Funds for the Central Universities, NSFC[21621001] ; 111 Project[B17020]
WOS研究方向
Chemistry
WOS类目
Chemistry, Physical
WOS记录号
WOS:000747885300001
出版者
EI入藏号
20220911728317
EI主题词
Crystals ; Intermetallics ; Palladium ; Palladium compounds
EI分类号
Metallurgy:531.1 ; Precious Metals:547.1 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Crystalline Solids:933.1
来源库
Web of Science
引用统计
被引频次[WOS]:6
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/273528
专题理学院_化学系
作者单位
1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
2.Jilin Univ, Coll Mat Sci & Engn, Changchun 130022, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
4.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
推荐引用方式
GB/T 7714
Li, Zhenyu,Zhao, Linmin,Chen, Hui,et al. Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties[J]. Catalysis Science & Technology,2022,12:1038-1042.
APA
Li, Zhenyu.,Zhao, Linmin.,Chen, Hui.,Liang, Xiao.,Ai, Xuan.,...&Zou, Xiaoxin.(2022).Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties.Catalysis Science & Technology,12,1038-1042.
MLA
Li, Zhenyu,et al."Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties".Catalysis Science & Technology 12(2022):1038-1042.
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