Early Precambrian tectono-thermal events: coupled U-Pb-Hf of detrital zircons from Jiao-Liao-Ji Belt, North China Craton

The Dashiqiao Formation on the Liaodong Peninsula constitutes an important component within the Jiao-Liao-Ji Belt, North China Craton. It is composed dominantly of dolomitic marbles intercalated with minor carbonaceous slates and mica schists, hosting one of the largest magnesite deposits on Earth. This study presents zircon cathodoluminescence (CL) images and U-Pb-Hf isotope data, as well as single-mineral geochemical data for the staurolite-garnet-mica schist from the Dashiqiao Formation, in order to constrain its protolith age and provenance, and further to discuss the early Precambrian tectono-thermal events of the North China Craton. U-Pb isotopic dating using the LA-ICP-MS method on detrital zircons from the schist preserves at least three age populations ranging in age from 2.99 to 2.02 Ga, and grains as old as ca 4087 Ma. The dominant Neoarchean detrital zircons were most probably sourced from the basement within the Longgang and Nangrim blocks, while the minor Mesoarchean zircons were only sourced from the Longgang Block. The subordinate middle Paleoproterozoic zircons are consistent with ages of the regionally distributed coeval Liaoji granites and volcanics within the Jiao-Liao-Ji Belt. Zircon U-Pb dating yields a metamorphic age of 1930 Ma for the sample, interpreted to represent the peak stage of epidote amphibolite facies metamorphism. Thus, the depositional age for the protolith of the schist was proposed in the period between 2.01 and 1.93 Ga. LA-MC-ICP-MS Lu-Hf isotopic data show that all Archean (2.45-2.55) detrital zircons possess positive epsilon(Hf)(t) values from + 0.7 to + 7.5 with juvenile depleted mantle model ages, suggesting a significant crustal growth event during the Neoarchean in the North China Craton. The Paleoproterozoic detrital zircons possess variable epsilon(Hf)(t) values (- 5.5-+ 8.3) and depleted mantle model ages from Mesoarchean to Paleoproterozoic. The zircons with negative epsilon(Hf)(t) values implies the Mesoarchean to Neoarchean crust undergoing a recycling event in the period 2.40-2.01 Ga, while those with positive epsilon(Hf)(t) value suggest some indication of juvenile addition to the crust during the Paleoproterozoic. Using regional geological and new detrital zricon U-Pb-Hf isotopic data, the early Precambrian tectono-thermal events can be subdivided into the following episodes: Mesoarchean, late Neoarchean, middle Paleoproterozoic, and late Paleoproterozoic times.