Michael Additions Catalyzed by a beta-Diketiminate-Supported Aluminum Complex

Liu, Zhizhou1; Vidovic, Dragoslav2

2018-05-04

10.1021/acs.joc.8b00434

JOURNAL OF ORGANIC CHEMISTRY   影响因子和分区

0022-3263

A beta-diketiminate-supported aluminum bistriflate complex ((LAl)-L-Dip(OTf)(2)center dot Na [BAr4Cl]; L-Dip = CH(CMe)(2)(N-C6H3-Pr-i(2))(2); Tf = O2SCF3; Ar-Cl = 3,5-Cl-2-C6H3) has been identified as an efficient Lewis acid catalyst for Michael additions involving numerous electron-rich (hetero)aromatic substrates and several alpha,beta-unsaturated carbonyl compounds. In a vast majority of the attempted Michael reactions our catalytic system was significantly superior over the currently used methods for the same transformations in terms of reaction times and temperatures, catalyst loadings, isolated product yields, and/or selectivity.

SCI ; EI ; IC ; CCR

英语

第一

Chemistry

Chemistry, Organic

WOS:000431726800039

AMER CHEMICAL SOC

20181905172265

Addition reactions ; Carbonyl compounds ; Catalyst selectivity ; Unsaturated compounds

Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1

CHEMISTRY

Web of Science

1.South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Peoples R China
2.Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

Liu, Zhizhou,Vidovic, Dragoslav. Michael Additions Catalyzed by a beta-Diketiminate-Supported Aluminum Complex[J]. JOURNAL OF ORGANIC CHEMISTRY,2018,83(9):5295-5300.

Liu, Zhizhou,&Vidovic, Dragoslav.(2018).Michael Additions Catalyzed by a beta-Diketiminate-Supported Aluminum Complex.JOURNAL OF ORGANIC CHEMISTRY,83(9),5295-5300.

Liu, Zhizhou,et al."Michael Additions Catalyzed by a beta-Diketiminate-Supported Aluminum Complex".JOURNAL OF ORGANIC CHEMISTRY 83.9(2018):5295-5300.