| 题名 | Development of a novel secondary phosphine oxide-ruthenium(II) catalyst and its application for carbonyl reduction |
| 作者 | |
| 通讯作者 | Chung, Lung Wa; Zhang, Xumu |
| 发表日期 | 2018-01-16
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| DOI | |
| 发表期刊 | |
| ISSN | 1359-7345
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| EISSN | 1364-548X
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| 卷号 | 54期号:5页码:535-538 |
| 摘要 | A secondary phosphine oxide-phosphine mixed tridentate ligand and its ruthenium complex have been developed. This complex shows excellent catalytic activity for carbonyl reduction, especially for the reduction of alpha,beta-unsaturated aldehydes. The turnover number and selectivity can reach up to 36500 and 99%, respectively. Control experiments and DFT calculations supported an outer-sphere mechanism during the hydrogenation reaction. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
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| 重要成果 | NI论文
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| 学校署名 | 第一
; 通讯
|
| 资助项目 | Shenzhen Science and Technology Innovation Committee[KQTD20150717103157174]
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| WOS研究方向 | Chemistry
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| WOS类目 | Chemistry, Multidisciplinary
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| WOS记录号 | WOS:000419995700025
|
| 出版者 | |
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：23
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/28149 |
| 专题 | 理学院_化学系 |
| 作者单位 | Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China |
| 第一作者单位 | 化学系 |
| 通讯作者单位 | 化学系 |
| 第一作者的第一单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Tan, Xuefeng,Zeng, Weijun,Zhang, Xiaoyong,et al. Development of a novel secondary phosphine oxide-ruthenium(II) catalyst and its application for carbonyl reduction[J]. CHEMICAL COMMUNICATIONS,2018,54(5):535-538.
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| APA |
Tan, Xuefeng,Zeng, Weijun,Zhang, Xiaoyong,Chung, Lung Wa,&Zhang, Xumu.(2018).Development of a novel secondary phosphine oxide-ruthenium(II) catalyst and its application for carbonyl reduction.CHEMICAL COMMUNICATIONS,54(5),535-538.
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| MLA |
Tan, Xuefeng,et al."Development of a novel secondary phosphine oxide-ruthenium(II) catalyst and its application for carbonyl reduction".CHEMICAL COMMUNICATIONS 54.5(2018):535-538.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| c7cc07647a.pdf（2321KB） | -- | -- | 限制开放 | -- | ||
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