题名 | Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W(V)-Co(II) cyanide single-chain magnet |
作者 | |
通讯作者 | Dunbar, Kim R. |
发表日期 | 2018-01-07
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DOI | |
发表期刊 | |
ISSN | 2041-6520
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EISSN | 2041-6539
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卷号 | 9期号:1页码:119-124 |
摘要 | A new octacyanotungstate(V) based single chain magnet {[(Tpm) Co(DMF) W(CN)(8)](2)[ Co(DMF)(4)]. 2DMF}(n) (1, Tpm 1/4 1,1, Tpm =1,1,1-trispyrazoylmethane), with an effective barrier of 39.7(3) cm(-1) is reported. The Ising- like magnetic anisotropy of the chain originates from the nearly parallel local orientations of the Co(II) ions with the source of the uniaxial magnetic anisotropy being a trigonal distortion of the octahedral environment with the fac-tridentate capping Tpm ligand. |
相关链接 | [来源记录] |
收录类别 | |
语种 | 英语
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重要成果 | NI论文
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学校署名 | 其他
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资助项目 | Robert A. Welch Foundation[A-1449]
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WOS研究方向 | Chemistry
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WOS类目 | Chemistry, Multidisciplinary
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WOS记录号 | WOS:000418376400013
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出版者 | |
EI入藏号 | 20175204588146
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EI主题词 | Chains
; Magnetic Anisotropy
; Magnetism
; Magnets
|
EI分类号 | Mechanical Drives:602.1
; Magnetism: Basic Concepts And Phenomena:701.2
|
来源库 | Web of Science
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引用统计 |
被引频次[WOS]:38
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成果类型 | 期刊论文 |
条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/28172 |
专题 | 理学院_化学系 |
作者单位 | 1.Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA 2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China |
第一作者单位 | 化学系 |
推荐引用方式 GB/T 7714 |
Zhang, Yuan-Zhu,Dolinar, Brian S.,Liu, Shihao,et al. Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W(V)-Co(II) cyanide single-chain magnet[J]. Chemical Science,2018,9(1):119-124.
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APA |
Zhang, Yuan-Zhu.,Dolinar, Brian S..,Liu, Shihao.,Brown, Andrew J..,Zhang, Xuan.,...&Dunbar, Kim R..(2018).Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W(V)-Co(II) cyanide single-chain magnet.Chemical Science,9(1),119-124.
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MLA |
Zhang, Yuan-Zhu,et al."Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W(V)-Co(II) cyanide single-chain magnet".Chemical Science 9.1(2018):119-124.
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条目包含的文件 | ||||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
c7sc02925j.pdf(992KB) | -- | -- | 开放获取 | -- | 浏览 |
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