| 题名 | Enantioselective Palladium-Catalyzed Decarboxylative Allylation of -Keto Esters Assisted by a Thiourea |
| 作者 | |
| 通讯作者 | Chung, Lung Wa; Zhang, Xumu |
| 发表日期 | 2018-01
|
| DOI | |
| 发表期刊 | |
| ISSN | 0936-5214
|
| EISSN | 1437-2096
|
| 卷号 | 29期号:1页码:51-56 |
| 摘要 | Enantioselective intramolecular decarboxylative allylation of -keto esters catalyzed by a palladium bis(phosphine)-thiourea complex is reported. This procedure is not only effective for -keto esters, but also effective for -keto amides. An intermolecular variant of the asymmetric decarboxylative allylation is also established. DFT calculations indicate that an outer-sphere mechanism is viable for the decarboxylative allylation of beta-keto esters. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 第一
; 通讯
|
| 资助项目 | Shenzhen Science and Technology Innovation Committee[KQTD20150717103157174]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Organic
|
| WOS记录号 | WOS:000418272700008
|
| 出版者 | |
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：6
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/28189 |
| 专题 | 理学院_化学系 |
| 作者单位 | South Univ Sci & Technol China, Dept Chem, 1088 Xueyuan Blvd, Shenzhen 518055, Guangdong, Peoples R China |
| 第一作者单位 | 化学系 |
| 通讯作者单位 | 化学系 |
| 第一作者的第一单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Qian, Hua,Gu, Guoxian,Zhou, Qinghai,et al. Enantioselective Palladium-Catalyzed Decarboxylative Allylation of -Keto Esters Assisted by a Thiourea[J]. SYNLETT,2018,29(1):51-56.
|
| APA |
Qian, Hua,Gu, Guoxian,Zhou, Qinghai,Lu, Jiaxiang,Chung, Lung Wa,&Zhang, Xumu.(2018).Enantioselective Palladium-Catalyzed Decarboxylative Allylation of -Keto Esters Assisted by a Thiourea.SYNLETT,29(1),51-56.
|
| MLA |
Qian, Hua,et al."Enantioselective Palladium-Catalyzed Decarboxylative Allylation of -Keto Esters Assisted by a Thiourea".SYNLETT 29.1(2018):51-56.
|
| 条目包含的文件 | 条目无相关文件。 | |||||
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
;
修改评论