题名 | Enantioselective alpha-C-H functionalization of amides with indoles triggered by radical trifluoromethylation of alkenes: Highly selective formation of C-CF3 and C-C bonds |
作者 | |
通讯作者 | Zhi, Yonggang; Liu, Xin-Yuan |
发表日期 | 2017-11
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DOI | |
发表期刊 | |
ISSN | 0022-1139
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EISSN | 1873-3328
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卷号 | 203页码:210-214 |
摘要 | A dual copper/chiral phosphoric acid-catalyzed asymmetric tandem remote C(sp(3))-H/unactivated alkene functionalization reaction triggered by radical trifluoromethylation of unactivated alkenes for the concomitant construction of C-CF3 and C-C bonds was described. This approach provided an efficient method for the synthesis of valuable chiral trifluoromethylated indole derivatives with excellent regio-, chemo-, and good enantioselectivity. (C) 2017 Elsevier B.V. All rights reserved. |
关键词 | |
相关链接 | [来源记录] |
收录类别 | |
语种 | 英语
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学校署名 | 通讯
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资助项目 | Shenzhen overseas high level talents innovation plan of technical innovation project[KQCX20150331101823702]
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WOS研究方向 | Chemistry
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WOS类目 | Chemistry, Inorganic & Nuclear
; Chemistry, Organic
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WOS记录号 | WOS:000418727100025
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出版者 | |
ESI学科分类 | CHEMISTRY
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来源库 | Web of Science
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引用统计 |
被引频次[WOS]:22
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成果类型 | 期刊论文 |
条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/28469 |
专题 | 理学院_化学系 |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China |
第一作者单位 | 化学系 |
通讯作者单位 | 化学系 |
推荐引用方式 GB/T 7714 |
Li, Taotao,Du, Yi-Meng,Lin, Jin-Shun,et al. Enantioselective alpha-C-H functionalization of amides with indoles triggered by radical trifluoromethylation of alkenes: Highly selective formation of C-CF3 and C-C bonds[J]. JOURNAL OF FLUORINE CHEMISTRY,2017,203:210-214.
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APA |
Li, Taotao,Du, Yi-Meng,Lin, Jin-Shun,Zhi, Yonggang,&Liu, Xin-Yuan.(2017).Enantioselective alpha-C-H functionalization of amides with indoles triggered by radical trifluoromethylation of alkenes: Highly selective formation of C-CF3 and C-C bonds.JOURNAL OF FLUORINE CHEMISTRY,203,210-214.
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MLA |
Li, Taotao,et al."Enantioselective alpha-C-H functionalization of amides with indoles triggered by radical trifluoromethylation of alkenes: Highly selective formation of C-CF3 and C-C bonds".JOURNAL OF FLUORINE CHEMISTRY 203(2017):210-214.
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条目包含的文件 | ||||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
li2017.pdf(1133KB) | -- | -- | 限制开放 | -- |
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