| 题名 | Organocatalytic regioselective, diastereoselective, and enantioselective annulation of cyclic 1-azadienes with gamma-nitro ketones via 3,4-cyclization |
| 作者 | |
| 通讯作者 | Li, Pengfei |
| 发表日期 | 2017-07
|
| DOI | |
| 发表期刊 | |
| ISSN | 2052-4129
|
| 卷号 | 4期号:7页码:1336-1340 |
| 摘要 | A regio-, diastereo-, and enantioselective [2 + 4] annulation reaction of cyclic 1-azadienes with gamma-nitro ketones is reported. In the presence of a chiral tertiary amine, the annulation reaction proceeded smoothly to furnish polysubstituted cyclohexanes in 43-95% yields with 80-98% ee via 3,4-addition. Notably, four consecutive stereocenters including one tetrasubstituted carbon stereocentre could be constructed in one-pot via this methodology. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 通讯
|
| 资助项目 | National Natural Science Foundation of China[NSFC 21302089]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Organic
|
| WOS记录号 | WOS:000405863700021
|
| 出版者 | |
| EI入藏号 | 20184806136959
|
| EI主题词 | Amines
; Ketones
|
| EI分类号 | Physical Chemistry:801.4
; Organic Compounds:804.1
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：26
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/28800 |
| 专题 | 理学院_化学系 |
| 作者单位 | South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China |
| 第一作者单位 | 化学系 |
| 通讯作者单位 | 化学系 |
| 第一作者的第一单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Yu, Lu,Cheng, Yuyu,Qi, Fei,et al. Organocatalytic regioselective, diastereoselective, and enantioselective annulation of cyclic 1-azadienes with gamma-nitro ketones via 3,4-cyclization[J]. Organic Chemistry Frontiers,2017,4(7):1336-1340.
|
| APA |
Yu, Lu,Cheng, Yuyu,Qi, Fei,Li, Rou,&Li, Pengfei.(2017).Organocatalytic regioselective, diastereoselective, and enantioselective annulation of cyclic 1-azadienes with gamma-nitro ketones via 3,4-cyclization.Organic Chemistry Frontiers,4(7),1336-1340.
|
| MLA |
Yu, Lu,et al."Organocatalytic regioselective, diastereoselective, and enantioselective annulation of cyclic 1-azadienes with gamma-nitro ketones via 3,4-cyclization".Organic Chemistry Frontiers 4.7(2017):1336-1340.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| c6qo00832a.pdf（866KB） | -- | -- | 限制开放 | -- | ||
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