| 题名 | Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes |
| 作者 | |
| 通讯作者 | Jiang, Wei |
| 发表日期 | 2017-06-28
|
| DOI | |
| 发表期刊 | |
| ISSN | 0002-7863
|
| 卷号 | 139期号:25页码:8436-8439 |
| 摘要 | Chiral epoxides are important intermedi- ates in chemistry and: biology. The high-throughput screening of asymmetric epoxidation conditions requires fast determination of the absolute configurations and ee values of chiral epoxides. Herein, we report molecular recognition and chiroptical sensing of epoxides in water using endo-functionalized molecular tubes. The absolute configurations and ee values were simultaneously determined by circular dichroism spectroscopy. In addition, real-time monitoring as well as the application to real asymmetric epoxidation was demonstrated. The method is simple, environmentally friendly, and amenable to high throughput screening. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI期刊
|
| 学校署名 | 第一
; 通讯
|
| 资助项目 | National Natural Science Foundation of China[21572097]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
|
| WOS记录号 | WOS:000404809600014
|
| 出版者 | |
| EI入藏号 | 20172703887651
|
| EI主题词 | Circular dichroism spectroscopy
; Dichroism
; Molecular recognition
; Throughput
|
| EI分类号 | Light/Optics:741.1
; Chemistry:801
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：121
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/28838 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.South Univ Sci & Technol China, Dept Chem, Xueyuan Blvd 1088, Shenzhen 518055, Peoples R China 2.Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China |
| 第一作者单位 | 化学系 |
| 通讯作者单位 | 化学系 |
| 第一作者的第一单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Wang, Li-Li,Chen, Zhao,Liu, Wei-Er,et al. Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes[J]. Journal of the American Chemical Society,2017,139(25):8436-8439.
|
| APA |
Wang, Li-Li,Chen, Zhao,Liu, Wei-Er,Ke, Hua,Wang, Sheng-Hua,&Jiang, Wei.(2017).Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes.Journal of the American Chemical Society,139(25),8436-8439.
|
| MLA |
Wang, Li-Li,et al."Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes".Journal of the American Chemical Society 139.25(2017):8436-8439.
|
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| Wang-2017-Molecular （921KB） | -- | -- | 限制开放 | -- | ||
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论