| 题名 | Titanium Imido Complexes by Displacement of -SiMe3 and C-H Bond Activation in a Ti-III Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC) |
| 作者 | |
| 通讯作者 | Tilley, T. Don |
| 发表日期 | 2017-05-10
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| DOI | |
| 发表期刊 | |
| ISSN | 1434-1948
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| EISSN | 1099-0682
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| 期号 | 18页码:2484-2487 |
| 摘要 | A strong sigma-donating cyclic (alkyl)(amino) carbene (cAAC) triggers rearrangement of the silyl(aryl) amido ligand -N(SiMe3)Dipp (Dipp = 2,6-diisopropylphenyl) in the coordination sphere of titanium(III) to afford a novel zwitterionic titanium imido complex with a TiCH2SiMe2[cAAC] linkage. Reduction of this species produces a new DippN=Ti imido complex containing a cAAC-centered radical species, characterized by single-crystal diffraction analysis and electron paramagnetic resonance spectroscopy. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
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| 学校署名 | 其他
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| 资助项目 | Joint Center for Artificial Photosynthesis, a U.S. Department of Energy, Office of Science, Basic Energy Sciences Innovation Hub[DE-SC0004993]
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| WOS研究方向 | Chemistry
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| WOS类目 | Chemistry, Inorganic & Nuclear
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| WOS记录号 | WOS:000401436900014
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| 出版者 | |
| ESI学科分类 | CHEMISTRY
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| 来源库 | Web of Science
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| 引用统计 |
被引频次[WOS]：2
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| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/28941 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA 2.Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA 3.South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China 4.Rensselaer Polytech Inst, Dept Chem & Chem Biol, Troy, NY 12180 USA 5.Rensselaer Polytech Inst, Baruch Ctr Biochem Solar Energy Res 60, Troy, NY 12180 USA |
| 第一作者单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Ye, Qing,Ziegler, Micah S.,Lakshmi, K. V.,et al. Titanium Imido Complexes by Displacement of -SiMe3 and C-H Bond Activation in a Ti-III Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2017(18):2484-2487.
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| APA |
Ye, Qing,Ziegler, Micah S.,Lakshmi, K. V.,&Tilley, T. Don.(2017).Titanium Imido Complexes by Displacement of -SiMe3 and C-H Bond Activation in a Ti-III Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(18),2484-2487.
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| MLA |
Ye, Qing,et al."Titanium Imido Complexes by Displacement of -SiMe3 and C-H Bond Activation in a Ti-III Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .18(2017):2484-2487.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| ejic.201700295.pdf（592KB） | -- | -- | 限制开放 | -- | ||
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