Facile Synthesis of the Dicyanophosphide Anion via Electrochemical Activation of White Phosphorus: An Avenue to Organophosphorus Compounds

Mei, Yanbo1,2; Yan, Zeen1,2; Liu, Liu Leo1,2

2022-02-02

10.1021/jacs.1c11087

Journal of the American Chemical Society   影响因子和分区

0002-7863

1520-5126

Organophosphorus compounds (OPCs) have gained tremendous interest in the past decades due to their wide applications ranging from synthetic chemistry to materials and biological sciences. We describe herein a practical and versatile approach for the transformation of white phosphorus (P-4) into useful OPCs with high P atom economy via a key bridging anion [P(CN)(2)](-). This anion can be prepared on a gram scale directly from P-4 through an electrochemical process. A variety of OPCs involving phosphinidenes, cyclophosphanes, and phospholides have been made readily accessible from P-4 in a two-step manner. Our approach has a significant impact on the future preparation of OPCs in laboratory and industrial settings.

SCI ; EI

英语

NI论文

第一 ; 通讯

National Natural Science Foundation of China[22101114] ; SUSTech startup fund[Y01216248] ; China Postdoctoral Science Foundation[2021M691420]

Chemistry

Chemistry, Multidisciplinary

WOS:000752956200007

AMER CHEMICAL SOC

20220511555587

Ions ; Phosphorus

Chemical Products Generally:804

Web of Science

1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China

Mei, Yanbo,Yan, Zeen,Liu, Liu Leo. Facile Synthesis of the Dicyanophosphide Anion via Electrochemical Activation of White Phosphorus: An Avenue to Organophosphorus Compounds[J]. Journal of the American Chemical Society,2022,144(4):1517-1522.

Mei, Yanbo,Yan, Zeen,&Liu, Liu Leo.(2022).Facile Synthesis of the Dicyanophosphide Anion via Electrochemical Activation of White Phosphorus: An Avenue to Organophosphorus Compounds.Journal of the American Chemical Society,144(4),1517-1522.

Mei, Yanbo,et al."Facile Synthesis of the Dicyanophosphide Anion via Electrochemical Activation of White Phosphorus: An Avenue to Organophosphorus Compounds".Journal of the American Chemical Society 144.4(2022):1517-1522.