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题名

Volume-expansion polymerization for UV-curable nanoimprinting

作者
通讯作者Cheng, Xing
发表日期
2017
DOI
发表期刊
ISSN
1071-1023
卷号35期号:1
摘要
In ultraviolet (UV) nanoimprinting, polymerization of liquid monomers is generally accompanied by a decrease in the resist volume, which often causes problems such as residual stress, pattern distortion, and replication defects. Thus, it is highly desirable to reduce or even eliminate volume shrinkage during monomer polymerization in UV nanoimprinting. To achieve this goal, monomers that undergo volume expansion during polymerization are added into the resist formulation. Spiro-orthocarbonate is a monomer that expands upon cationic ring-opening polymerization. By mixing the spiro-orthocarbonate monomer with a common epoxy monomer, the authors achieved a zero volume change after curing. It is also possible to achieve volume expansion in this new resist formulation. The residual stress in the cured resist structures is also effectively mitigated. It is expected that elimination of volume shrinkage in UV nanoimprinting can address important issues such as pattern fidelity and high demolding forces. (C) 2017 American Vacuum Society.
相关链接[来源记录]
收录类别
SCI ; EI
语种
英语
学校署名
通讯
资助项目
Shenzhen Science and Technology Innovation Committee for basic science[JCYJ20140417105742711]
WOS研究方向
Engineering ; Science & Technology - Other Topics ; Physics
WOS类目
Engineering, Electrical & Electronic ; Nanoscience & Nanotechnology ; Physics, Applied
WOS记录号
WOS:000395468500035
出版者
EI入藏号
20170203238661
EI主题词
Cationic polymerization ; Curing ; Expansion ; Monomers ; Nanoimprint lithography ; Residual stresses ; Shrinkage
EI分类号
Nanotechnology:761 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Polymerization:815.2 ; Solid State Physics:933 ; Materials Science:951
ESI学科分类
MATERIALS SCIENCE
来源库
Web of Science
引用统计
被引频次[WOS]:7
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/29222
专题工学院_材料科学与工程系
作者单位
1.Texas A&M Univ, Dept Elect & Comp Engn, College Stn, TX 77843 USA
2.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen Key Lab Nanoimprint Technol, 1088 Xueyuan Blvd, Shenzhen 518055, Guangdong, Peoples R China
通讯作者单位材料科学与工程系
推荐引用方式
GB/T 7714
Luo, Bingqing,Fan, Zengju,Li, Ziping,et al. Volume-expansion polymerization for UV-curable nanoimprinting[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B,2017,35(1).
APA
Luo, Bingqing,Fan, Zengju,Li, Ziping,Chen, Yulong,Tian, Yanqing,&Cheng, Xing.(2017).Volume-expansion polymerization for UV-curable nanoimprinting.JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B,35(1).
MLA
Luo, Bingqing,et al."Volume-expansion polymerization for UV-curable nanoimprinting".JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B 35.1(2017).
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