A facile molecularly engineered copper (II) phthalocyanine as hole transport material for planar perovskite solar cells with enhanced performance and stability

Yang, Guang1; Wang, Yu-Long2; Xu, Jia-Ju2; Lei, Hong-Wei1; Chen, Cong1; Shan, Hai-Quan2; Liu, Xiao-Yuan2; Xu, Zong-Xiang2; Fang, Guo-Jia1

2017-01

10.1016/j.nanoen.2016.11.039

Nano Energy   影响因子和分区

2211-2855

2211-3282

Perovskite solar cells (PSCs) demonstrate huge potential in photovoltaic conversion, yet their practical applications face one major obstacle: their instability. As to conventional hole transport materials (HTMs) such as spiro-OMeTAD, their future commercialization maybe hampered for the cost and instability. Here, we report a new HTM of copper (II) phthalocyanine with octamethyl-substituted function groups (CuMe2Pc). Unlike the normal edge on orientation of pristine copper (II) phthalocyanine (CuPc), we found that CuMe2Pc could form face-on molecular alignment when deposited on perovskite via vacuum thermal evaporation, resulting in higher hole mobility, more condense thin film structure and more hydrophobic surface. These properties are more favorable for hole transport and moisture resistance applications in PSCs. PSCs with planar structure were fabricated and tested, utilizing different phthalocyanines and spiro-OMeTAD as HTMs. PSCs with CuMe2Pc showed 25% higher power conversion efficiency (PCE) compared with those with CuPc. Furthermore, beneficial from the hydrophobic nature of CuMe2Pc, the devices with CuMe2Pc as HTM show improved stability and retained over 95% of their initial efficiencies even after storage in the humidity about 50% for 2000 h without encapsulation. This study demonstrates that CuMe2Pc is a potential HTM for fabricating low-cost and efficient PSCs with long-term stability.

Hole transport materials Copper (II) phthalocyanine Octamethyl-substituted Molecular alignment Long-term stability

SCI ; EI

英语

通讯

Special Funds for the Development of Strategic Emerging Industries in Shenzhen[JCYJ20160523160822851] ; Special Funds for the Development of Strategic Emerging Industries in Shenzhen[JCYJ20150630145302239]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied

WOS:000393446500037

ELSEVIER SCIENCE BV

20164903090541

Efficiency ; Hole mobility ; Hydrophobicity ; Molecular orientation ; Perovskite ; Perovskite solar cells ; Photoconducting materials ; Solar cells ; Solar power generation ; Stability ; Surface chemistry ; Thermal evaporation ; Vacuum evaporation

Minerals:482.2 ; Solar Power:615.2 ; Vacuum Applications:633.1 ; Solar Cells:702.3 ; Semiconducting Materials:712.1 ; Physical Chemistry:801.4 ; Production Engineering:913.1 ; Mechanics:931.1 ; Physical Properties of Gases, Liquids and Solids:931.2

Web of Science

1.Wuhan Univ, Sch Phys & Technol, Minist Educ China, Key Lab Artificial Micro & Nanostruct, Wuhan 430072, Peoples R China
2.South Univ Sci & Technol China, Dept Chem, Shenzhen, Guangdong 518000, Peoples R China

Yang, Guang,Wang, Yu-Long,Xu, Jia-Ju,et al. A facile molecularly engineered copper (II) phthalocyanine as hole transport material for planar perovskite solar cells with enhanced performance and stability[J]. Nano Energy,2017,31:322-330.

Yang, Guang.,Wang, Yu-Long.,Xu, Jia-Ju.,Lei, Hong-Wei.,Chen, Cong.,...&Fang, Guo-Jia.(2017).A facile molecularly engineered copper (II) phthalocyanine as hole transport material for planar perovskite solar cells with enhanced performance and stability.Nano Energy,31,322-330.

Yang, Guang,et al."A facile molecularly engineered copper (II) phthalocyanine as hole transport material for planar perovskite solar cells with enhanced performance and stability".Nano Energy 31(2017):322-330.