| 题名 | Asymmetric synthesis of chromene skeletons via organocatalytic domino reactions of in situ generated ortho-quinone methide with malononitrile and beta-functionalized ketone |
| 作者 | |
| 通讯作者 | Li, Wenjun |
| 发表日期 | 2017
|
| DOI | |
| 发表期刊 | |
| ISSN | 2046-2069
|
| EISSN | 2046-2069
|
| 卷号 | 7期号:62页码:39216-39220 |
| 摘要 | Enantioselective organocatalytic domino reactions of in situ generated ortho-quinone methides with malononitrile and beta-functionalized ketones have been developed. This strategy could generate various chiral chromenes in high yields (up to 99%) and stereoselectivities (up to >99 : 1 e.r.) in the presence of 5 mol% of a bifunctional organocatalyst. Gram-scale and useful synthetic transformations of this process are also presented. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 其他
|
| 资助项目 | National Natural Science Foundation of China[21502043]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
|
| WOS记录号 | WOS:000407762300056
|
| 出版者 | |
| EI入藏号 | 20173304052638
|
| EI主题词 | Ketones
; Reaction Kinetics
|
| EI分类号 | Chemical Reactions:802.2
; Organic Compounds:804.1
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：77
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/29246 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Qingdao Univ, Sch Pharm, Dept Med Chem, Qingdao 266021, Peoples R China 2.South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Peoples R China |
| 推荐引用方式 GB/T 7714 |
Zhang, Lili,Zhou, Xiao,Li, Pengfei,et al. Asymmetric synthesis of chromene skeletons via organocatalytic domino reactions of in situ generated ortho-quinone methide with malononitrile and beta-functionalized ketone[J]. RSC Advances,2017,7(62):39216-39220.
|
| APA |
Zhang, Lili.,Zhou, Xiao.,Li, Pengfei.,Liu, Zhantao.,Liu, Yang.,...&Li, Wenjun.(2017).Asymmetric synthesis of chromene skeletons via organocatalytic domino reactions of in situ generated ortho-quinone methide with malononitrile and beta-functionalized ketone.RSC Advances,7(62),39216-39220.
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| MLA |
Zhang, Lili,et al."Asymmetric synthesis of chromene skeletons via organocatalytic domino reactions of in situ generated ortho-quinone methide with malononitrile and beta-functionalized ketone".RSC Advances 7.62(2017):39216-39220.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| c7ra08157j.pdf（886KB） | -- | -- | 开放获取 | -- | 浏览 | |
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