| 题名 | Catalytic Enantioselective Total Synthesis of Hypocrolide A |
| 作者 | |
| 通讯作者 | Li, Chuang-Chuang |
| 发表日期 | 2016-10-07
|
| DOI | |
| 发表期刊 | |
| ISSN | 1523-7060
|
| EISSN | 1523-7052
|
| 卷号 | 18期号:19页码:4932-4935 |
| 摘要 | The first and catalytic enantioselective total synthesis of hypocrolide A (>99% ee) in 12 steps, as well as other botryanes, is described. The absolute configurations of these compounds have been unambiguously confirmed or reassigned accordingly. The key reactions in this study include an unusual rhodium-catalyzed intramolecular [4 + 2] cycloaddition and a biomimetic oxidative [3 + 2] cycloaddition based on our revised biogenetic pathway. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI期刊
|
| 学校署名 | 通讯
|
| 资助项目 | Shenzhen Science and Technology Innovation Committee[JSGG20160301103446375]
; Shenzhen Science and Technology Innovation Committee[KQTD2015071710315717]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Organic
|
| WOS记录号 | WOS:000385053900045
|
| 出版者 | |
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：20
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/29414 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen 518055, Peoples R China 2.South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Peoples R China |
| 第一作者单位 | 化学系 |
| 通讯作者单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Qiao, Chuang,Zhang, Wen,Han, Jing-Chun,et al. Catalytic Enantioselective Total Synthesis of Hypocrolide A[J]. ORGANIC LETTERS,2016,18(19):4932-4935.
|
| APA |
Qiao, Chuang,Zhang, Wen,Han, Jing-Chun,&Li, Chuang-Chuang.(2016).Catalytic Enantioselective Total Synthesis of Hypocrolide A.ORGANIC LETTERS,18(19),4932-4935.
|
| MLA |
Qiao, Chuang,et al."Catalytic Enantioselective Total Synthesis of Hypocrolide A".ORGANIC LETTERS 18.19(2016):4932-4935.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| acs.orglett.6b02414.（1089KB） | -- | -- | 限制开放 | -- | ||
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