中文版 | English
题名

A highly efficient PtCo/C electrocatalyst for the oxygen reduction reaction

作者
通讯作者Li, Hui; Bi, Xiaotao T.; Wang, Haijiang
发表日期
2016
DOI
发表期刊
ISSN
2046-2069
EISSN
2046-2069
卷号6期号:41页码:34484-34491
摘要
In this study, we report a novel and simple synthesis strategy to fabricate a leached PtCo/C electrocatalyst, which involves no hydrogen and protective agent in the preparation process. This method is composed of a chemical impregnation, a heat treatment and a leaching procedure, producing PtCo nanoparticles of 4.7 +/- 0.5 nm, slightly larger than the size of the PtCo nanoparticles prepared by a tetraoctylammonium bromide (TOAB)-assisted approach in which TOAB serves as a protective agent preventing the agglomeration of the alloy nanoparticles. After the leaching, the as-synthesized leached PtCo/C catalyst demonstrates a comparable oxygen reduction reaction mass activity to that of the TOAB-assisted leached PtCo/C catalyst, which is ca. 2-fold enhancement compared with the in-house Pt(50 wt%)/C and commercial Pt/C (TKK) catalysts.
相关链接[来源记录]
收录类别
SCI ; EI
语种
英语
学校署名
通讯
资助项目
Natural Sciences and Engineering Research Council of Canada Collaborative Research and Development (NSERC-CRD)[452756-13]
WOS研究方向
Chemistry
WOS类目
Chemistry, Multidisciplinary
WOS记录号
WOS:000374049700047
出版者
EI入藏号
20161802333331
EI主题词
Binary alloys ; Cobalt alloys ; Electrocatalysts ; Electrolytic reduction ; Heating ; Leaching ; Nanoparticles ; Oxygen ; Uranium alloys
EI分类号
Minor, Precious and Rare Earth Metals and Alloys:547 ; Precious Metals:547.1 ; Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Nanotechnology:761 ; Chemical Reactions:802.2 ; Chemical Operations:802.3 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Solid State Physics:933
来源库
Web of Science
引用统计
被引频次[WOS]:12
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/29825
专题工学院_材料科学与工程系
作者单位
1.Univ British Columbia, Dept Chem & Biol Engn, 2360 East Mall, Vancouver, BC V6T 1Z3, Canada
2.Vancouver Int Clean Tech Res Inst Inc, 4475 Wayburne Dr, Burnaby, BC V5G 4X4, Canada
3.South Univ Sci & Technol, Dept Mat Sci & Engn, 1088 Xueyuan Rd, Shenzhen, Guangdong, Peoples R China
通讯作者单位材料科学与工程系
推荐引用方式
GB/T 7714
Wang, Yan-Jie,Zhao, Nana,Fang, Baizeng,et al. A highly efficient PtCo/C electrocatalyst for the oxygen reduction reaction[J]. RSC Advances,2016,6(41):34484-34491.
APA
Wang, Yan-Jie,Zhao, Nana,Fang, Baizeng,Li, Hui,Bi, Xiaotao T.,&Wang, Haijiang.(2016).A highly efficient PtCo/C electrocatalyst for the oxygen reduction reaction.RSC Advances,6(41),34484-34491.
MLA
Wang, Yan-Jie,et al."A highly efficient PtCo/C electrocatalyst for the oxygen reduction reaction".RSC Advances 6.41(2016):34484-34491.
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