| 题名 | Synthetic strategies toward the decalin motif of maklamicin and related spirotetronates |
| 作者 | |
| 通讯作者 | Lacoske, Michelle H. |
| 发表日期 | 2015
|
| DOI | |
| 发表期刊 | |
| ISSN | 2052-4129
|
| 卷号 | 2期号:4页码:388-393 |
| 摘要 | Herein we describe a scalable approach to the decalin moiety of maklamicin. Key to the synthesis is an intramolecular Diels-Alder (IMDA) reaction that proceeds via an endo-axial transition state to generate the desired stereochemistry. We explored the diastereoselectivity of the IMDA reaction as a function of both chiral catalysis and acyclic precursor stereochemistry. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 其他
|
| 资助项目 | U.S. Department of Education through GAANN[P200A120223]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Organic
|
| WOS记录号 | WOS:000364444500016
|
| 出版者 | |
| EI入藏号 | 20184806136249
|
| EI主题词 | Organic solvents
; Stereochemistry
; Stereoselectivity
|
| EI分类号 | Chemistry:801
; Chemical Reactions:802.2
; Chemical Agents and Basic Industrial Chemicals:803
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：5
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/30069 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA 2.South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 |
Lacoske, Michelle H.,Xu, Jing,Mansour, Noel,et al. Synthetic strategies toward the decalin motif of maklamicin and related spirotetronates[J]. Organic Chemistry Frontiers,2015,2(4):388-393.
|
| APA |
Lacoske, Michelle H.,Xu, Jing,Mansour, Noel,Gao, Chao,&Theodorakis, Emmanuel A..(2015).Synthetic strategies toward the decalin motif of maklamicin and related spirotetronates.Organic Chemistry Frontiers,2(4),388-393.
|
| MLA |
Lacoske, Michelle H.,et al."Synthetic strategies toward the decalin motif of maklamicin and related spirotetronates".Organic Chemistry Frontiers 2.4(2015):388-393.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| Lacoske-2015-Synthet（2763KB） | -- | -- | 限制开放 | -- | ||
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