| 题名 | Palladium/Copper Complexes Co-Catalyzed Highly Enantioselective Ring Opening Reaction of Azabenzonorbornadienes with Terminal Alkynes |
| 作者 | |
| 通讯作者 | Fan, Baomin |
| 发表日期 | 2013-10-11
|
| DOI | |
| 发表期刊 | |
| ISSN | 1615-4150
|
| EISSN | 1615-4169
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| 卷号 | 355期号:14-15页码:2827-2832 |
| 摘要 | A chiral palladium/copper (Pd/Cu) co-catalytic system which could enable asymmetric ring opening reaction of azabenzonorbornadienes with terminal alkynes is reported. This system comprises palladium(II) acetate [Pd(OAc)(2)]/(R)-xyl-Binap and copper(I) triflate (CuOTf). A good substrate scope was found, with excellent enantioselective outcomes (up to >99.9% ee). A reaction mechanism involving two metal complexes is also proposed. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 其他
|
| 资助项目 | State Key Laboratory of Elemento-organic Chemistry, Nankai University[201206]
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| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Applied
; Chemistry, Organic
|
| WOS记录号 | WOS:000328149300015
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| 出版者 | |
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：40
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| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/30306 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Yunnan Univ Nationalities, Key Lab Chem Ethn Med Resources, State Ethn Affairs Commiss, Kunming 650500, Peoples R China 2.Yunnan Univ Nationalities, Minist Educ, Kunming 650500, Peoples R China 3.South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 |
Fan, Baomin,Li, Sifeng,Chen, Hualei,et al. Palladium/Copper Complexes Co-Catalyzed Highly Enantioselective Ring Opening Reaction of Azabenzonorbornadienes with Terminal Alkynes[J]. ADVANCED SYNTHESIS & CATALYSIS,2013,355(14-15):2827-2832.
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| APA |
Fan, Baomin.,Li, Sifeng.,Chen, Hualei.,Lu, Zhiwu.,Liu, Shanshan.,...&Wang, Jun.(2013).Palladium/Copper Complexes Co-Catalyzed Highly Enantioselective Ring Opening Reaction of Azabenzonorbornadienes with Terminal Alkynes.ADVANCED SYNTHESIS & CATALYSIS,355(14-15),2827-2832.
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| MLA |
Fan, Baomin,et al."Palladium/Copper Complexes Co-Catalyzed Highly Enantioselective Ring Opening Reaction of Azabenzonorbornadienes with Terminal Alkynes".ADVANCED SYNTHESIS & CATALYSIS 355.14-15(2013):2827-2832.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| 10.1002adsc.20130074（192KB） | -- | -- | 限制开放 | -- | ||
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