Metal-Free and Metallated Polymers: Properties and Photovoltaic Performance

Ng, Annie1; Ho, Cheuk-Lam2,3; Fung, Man Kin1; Sun, Ye Chuan1; Shao, Shu-Yan4; Fu, Ying-Ying4; Ng, Alan Man Ching1,5; Li, Chi Ho6; Cheung, Wai Kei6; Leung, Yu Hang1; Djurisic, Aleksandra B.1; Wang, Qiwei2,3; He, Ze2,3; Wang, Xingzhu2,3; Chan, Wai-Kin6; Xie, Zhi-Yuan4; Zapien, Juan Antonio7; To, Chap Hang7; Wong, Wai-Yeung2,3

2012-07-13

10.1002/macp.201100686

MACROMOLECULAR CHEMISTRY AND PHYSICS   影响因子和分区

1022-1352

We have studied the properties of organic and organometallic polymers based on a similar chemical structure to elucidate the influence of the metal center on the optical and electronic properties of the polymers as well as their photovoltaic performance. Detailed characterization of the optical properties of both polymers is performed and film morphology and photovoltaic performance are compared. Metal-containing polymers exhibit red-shifted absorption and under optimal processing conditions exhibit different film morphology compared with the metal-free ones. Our results indicate that organometallic polymers represent a promising class of compounds for improved performance in photovoltaic cells.

alkyne metallopolymer photovoltaics solar cell transition metal

SCI ; EI

英语

其他

Hong Kong Baptist University[FRG2/09-10/091]

Polymer Science

Polymer Science

WOS:000306082100001

WILEY-V C H VERLAG GMBH

20122915251274

Electronic properties ; Morphology ; Organometallics ; Phase separation ; Photoelectrochemical cells ; Photovoltaic cells ; Red Shift ; Solar cells ; Solar power generation ; Transition metals

Metallurgy and Metallography:531 ; Solar Power:615.2 ; Thermodynamics:641.1 ; Electric Batteries:702.1 ; Solar Cells:702.3 ; Organic Compounds:804.1 ; Organic Polymers:815.1.1 ; Materials Science:951

CHEMISTRY

Web of Science

1.Univ Hong Kong, Dept Phys, Hong Kong, Hong Kong, Peoples R China
2.Hong Kong Baptist Univ, Inst Mol Funct Mat, Kowloon Tong, Hong Kong, Peoples R China
3.Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China
4.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
5.S Univ Sci & Technol China, Div Phys Sci, Nanostruct Inst Energy & Environm Res, Shenzhen, Peoples R China
6.Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
7.City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China

Ng, Annie,Ho, Cheuk-Lam,Fung, Man Kin,et al. Metal-Free and Metallated Polymers: Properties and Photovoltaic Performance[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2012,213(13):1300-1310.

Ng, Annie.,Ho, Cheuk-Lam.,Fung, Man Kin.,Sun, Ye Chuan.,Shao, Shu-Yan.,...&Wong, Wai-Yeung.(2012).Metal-Free and Metallated Polymers: Properties and Photovoltaic Performance.MACROMOLECULAR CHEMISTRY AND PHYSICS,213(13),1300-1310.

Ng, Annie,et al."Metal-Free and Metallated Polymers: Properties and Photovoltaic Performance".MACROMOLECULAR CHEMISTRY AND PHYSICS 213.13(2012):1300-1310.