南方科技大学知识苑(SUSTech KC): Highly Enantioselective Rhodium(I)-Catalyzed Alder-ene-type Cycloisomerization of 1,7-Enynes

题名	Highly Enantioselective Rhodium(I)-Catalyzed Alder-ene-type Cycloisomerization of 1,7-Enynes
作者	Zeng，Jingwen 1; Fang，Wei1 ; Lin，Bijin1 ; Chen，Gen Qiang2 ; Zhang，Xumu1
通讯作者	Zhang，Xumu
发表日期	2022-01-14
DOI	10.1021/acs.orglett.1c04171
发表期刊	ORGANIC LETTERS 影响因子和分区
ISSN	1523-7060
EISSN	1523-7052
卷号	24 期号:3页码:869-874
摘要	The transition-metal-catalyzed asymmetric cycloisomerization of 1,7-enynes is regarded as a formidable challenge due to the poor ability of 1,7-enynes to serve as bidentate ligands to metal. In this Letter, a highly enantioselective rhodium(I)-catalyzed Alder-ene-type cycloisomerization of 1,7-enynes is disclosed, offering an efficient method for the synthesis of a wide range of fused six-membered cyclic compounds. Furthermore, a high turnover frequency experiment and deuterium-labeling experiment were performed to give insight into this transformation.
相关链接	[Scopus记录]
收录类别	SCI
语种	英语
重要成果	NI论文
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China[21901107,22171129,21991113] ; Shenzhen Science and Technology Innovation Committee[
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000776092500014
出版者	AMER CHEMICAL SOC
ESI学科分类	CHEMISTRY
Scopus记录号	2-s2.0-85123901449
来源库	Scopus
引用统计	被引频次[WOS]：8
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/327778
专题	理学院_化学系前沿与交叉科学研究院
作者单位	1.Medi-X Pingshan and Department of Chemistry,Southern University of Science and Technology,Shenzhen,518000,China 2.Academy for Advanced Interdisciplinary Studies,Guangdong Provincial Key Laboratory of Catalysis,Southern University of Science and Technology,Shenzhen,518055,China
第一作者单位	化学系
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Zeng，Jingwen,Fang，Wei,Lin，Bijin,et al. Highly Enantioselective Rhodium(I)-Catalyzed Alder-ene-type Cycloisomerization of 1,7-Enynes[J]. ORGANIC LETTERS,2022,24(3):869-874.
APA	Zeng，Jingwen,Fang，Wei,Lin，Bijin,Chen，Gen Qiang,&Zhang，Xumu.(2022).Highly Enantioselective Rhodium(I)-Catalyzed Alder-ene-type Cycloisomerization of 1,7-Enynes.ORGANIC LETTERS,24(3),869-874.
MLA	Zeng，Jingwen,et al."Highly Enantioselective Rhodium(I)-Catalyzed Alder-ene-type Cycloisomerization of 1,7-Enynes".ORGANIC LETTERS 24.3(2022):869-874.