南方科技大学知识苑(SUSTech KC): Synthesis of Single-Layer Two-Dimensional Metal-Organic Frameworks M-3(HAT)(2) (M = Ni, Fe, Co, HAT=1,4,5,8,9,12-hexaazatriphenylene) Using an On-Surface Reaction

题名	Synthesis of Single-Layer Two-Dimensional Metal-Organic Frameworks M-3(HAT)(2) (M = Ni, Fe, Co, HAT=1,4,5,8,9,12-hexaazatriphenylene) Using an On-Surface Reaction
作者	Lyu, Cheng-Kun 1; Gao, Yi-Fan1,2 ; Gao, Zi-Ang 1; Mo, Song-Yu 1; Hua, Mu-Qing 1; Li, En 1; Fu, Shu-Qing 3,4; Chen, Jia-Yan 3,4; Liu, Pei-Nian 3,4; Huang, Li2 ; Lin, Nian 1
通讯作者	Lin, Nian
发表日期	2022-05-01
DOI	10.1002/anie.202204528
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 影响因子和分区
ISSN	1433-7851
EISSN	1521-3773
卷号	61
摘要	1,4,5,8,9,12-Hexaazatriphenylene (HAT) is one of the smallest polyheterocyclic aromatic building blocks for forming conjugated metal-organic frameworks (cMOFs). However, the strong inter-molecular steric hindrance impedes the growth of HAT-based cMOFs. Here we employ on-surface synthesis to grow single-layer two-dimensional cMOFs of M-3(HAT)(2) (M= Ni, Fe, Co). Using scanning tunnelling microscopy and density-functional theory (DFT) analysis, we resolve that the frameworks comprise a hexagonal lattice of HAT molecules and a Kagome lattice of metal atoms. The DFT analysis indicates that Ni, Co and Fe carry a magnetic moment of 1.1, 2.5, and 3.7 mu B, respectively. We anticipate that the small a-conjugated core of HAT and strong bidentate chelating coordination give rise to appealing electronic and magnetic properties.
关键词	2D Materials Conjugated Metal-Organic Frameworks On-Surface Synthesis Scanning Tunnelling Microscopy
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
重要成果	NI论文
学校署名	其他
资助项目	Hong Kong RGC[16301820,163001219]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000790974700001
出版者	WILEY-V C H VERLAG GMBH
EI入藏号	20221912072386
EI主题词	Density functional theory ; Lattice theory ; Magnetic moments ; Metals ; Surface reactions
EI分类号	Magnetism: Basic Concepts and Phenomena:701.2 ; Chemical Reactions:802.2 ; Probability Theory:922.1 ; Mathematical Statistics:922.2 ; Atomic and Molecular Physics:931.3 ; Quantum Theory; Quantum Mechanics:931.4
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：20
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/334338
专题	理学院_物理系
作者单位	1.Hong Kong Univ Sci & Technol, Dept Phys, Hong Kong, Peoples R China 2.Southern Univ Sci & Technol, Dept Phys, Shenzhen 518055, Guangdong, Peoples R China 3.East China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Meilong Rd 130, Shanghai, Peoples R China 4.East China Univ Sci & Technol, Inst Fine Chem, Meilong Rd 130, Shanghai, Peoples R China
推荐引用方式 GB/T 7714	Lyu, Cheng-Kun,Gao, Yi-Fan,Gao, Zi-Ang,et al. Synthesis of Single-Layer Two-Dimensional Metal-Organic Frameworks M-3(HAT)(2) (M = Ni, Fe, Co, HAT=1,4,5,8,9,12-hexaazatriphenylene) Using an On-Surface Reaction[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022,61.
APA	Lyu, Cheng-Kun.,Gao, Yi-Fan.,Gao, Zi-Ang.,Mo, Song-Yu.,Hua, Mu-Qing.,...&Lin, Nian.(2022).Synthesis of Single-Layer Two-Dimensional Metal-Organic Frameworks M-3(HAT)(2) (M = Ni, Fe, Co, HAT=1,4,5,8,9,12-hexaazatriphenylene) Using an On-Surface Reaction.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,61.
MLA	Lyu, Cheng-Kun,et al."Synthesis of Single-Layer Two-Dimensional Metal-Organic Frameworks M-3(HAT)(2) (M = Ni, Fe, Co, HAT=1,4,5,8,9,12-hexaazatriphenylene) Using an On-Surface Reaction".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 61(2022).