Transition-metal-free regioselective and stereoselective C(sp(2))-C(sp(3)) coupling of enamides with ethers or alkanes via photoredox-catalyzed cross-dehydrogenative coupling reactions

Tao, Ji-Yu1; Wang, Ying-Xue1; Zhang, Qing-Hong1; Ni, Kun1; Zhu, Tong-Hao4; Zhao, Kai1,2,3

2022-04-01

10.1039/d2gc00472k

GREEN CHEMISTRY   影响因子和分区

1463-9262

1463-9270

A generally applicable and robust regio- and stereoselective cross-dehydrogenative-coupling of enamides with ethers or alkanes via transition-metal-free photoredox-catalysis under environmentally benign and atom economic conditions is demonstrated. The visible-light-induced transformations proceed smoothly with the aid of non-expensive and non-poisonous organic dyes, forging geometrically defined and synthetically paramount beta-alkylated enamides with broad substituent diversity and functional group compatibility.

SCI ; EI

英语

通讯

National Natural Science Foundation of China[21801129] ; Natural Science Research Projects in Jiangsu Higher Education Institutions[18KJB150018] ; Nanjing Tech University[39837137] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Soochow University[KJS1945]

Chemistry ; Science & Technology - Other Topics

Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology

WOS:000793305200001

ROYAL SOC CHEMISTRY

20222412206581

Catalysis ; Paraffins ; Stereoselectivity ; Transition metals

Metallurgy and Metallography:531 ; Chemistry:801 ; Chemical Reactions:802.2 ; Organic Compounds:804.1

CHEMISTRY

Web of Science

1.Nanjing Tech Univ, Sch Chem & Mol Engn, Jiangsu Natl Synerget Innovat Ctr Adv Mat, Inst Adv Synth, Nanjing 211816, Peoples R China
2.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
3.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China
4.Taizhou Univ, Inst Adv Studies, 1139 Shifu Ave, Taizhou 318000, Peoples R China

Tao, Ji-Yu,Wang, Ying-Xue,Zhang, Qing-Hong,et al. Transition-metal-free regioselective and stereoselective C(sp(2))-C(sp(3)) coupling of enamides with ethers or alkanes via photoredox-catalyzed cross-dehydrogenative coupling reactions[J]. GREEN CHEMISTRY,2022,24:4004-4011.

Tao, Ji-Yu,Wang, Ying-Xue,Zhang, Qing-Hong,Ni, Kun,Zhu, Tong-Hao,&Zhao, Kai.(2022).Transition-metal-free regioselective and stereoselective C(sp(2))-C(sp(3)) coupling of enamides with ethers or alkanes via photoredox-catalyzed cross-dehydrogenative coupling reactions.GREEN CHEMISTRY,24,4004-4011.

Tao, Ji-Yu,et al."Transition-metal-free regioselective and stereoselective C(sp(2))-C(sp(3)) coupling of enamides with ethers or alkanes via photoredox-catalyzed cross-dehydrogenative coupling reactions".GREEN CHEMISTRY 24(2022):4004-4011.