南方科技大学知识苑(SUSTech KC): Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of alpha-thioesters

题名	Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of alpha-thioesters
作者	Sun, Yu-Tuo 1,2,3; Rao, Xiaofeng1,2 ; Xu, Weici1,2 ; Xu, Ming-Hua1,2
通讯作者	Xu, Ming-Hua
发表日期	2022-05-01
DOI	10.1039/d2qo00164k
发表期刊	Organic Chemistry Frontiers 影响因子和分区
ISSN	2052-4129
摘要	Asymmetric construction of C-S bonds through transition-metal catalysis is a challenging subject. By using chiral diene as the ligand, we have developed the first rhodium(i)-catalyzed asymmetric carbene insertion approach for C-S bond formation to access sulfur-substituted stereocenters under mild conditions, allowing the facile synthesis of a range of potentially valuable alpha-thioesters in high yields with moderate to good enantioselectivities.
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China[21971103] ; Shenzhen Science and Technology Innovation Commission[JCYJ20200109141408054] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000796594700001
出版者	ROYAL SOC CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：16
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/335001
专题	深圳格拉布斯研究院理学院_化学系
作者单位	1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, 1088 Xueyuan Blvd, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, 1088 Xueyuan Blvd, Shenzhen 518055, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Mat Med, 555 Chongzhi Rd, Shanghai 201203, Peoples R China
第一作者单位	深圳格拉布斯研究院; 化学系
通讯作者单位	深圳格拉布斯研究院; 化学系
第一作者的第一单位	深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Sun, Yu-Tuo,Rao, Xiaofeng,Xu, Weici,et al. Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of alpha-thioesters[J]. Organic Chemistry Frontiers,2022.
APA	Sun, Yu-Tuo,Rao, Xiaofeng,Xu, Weici,&Xu, Ming-Hua.(2022).Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of alpha-thioesters.Organic Chemistry Frontiers.
MLA	Sun, Yu-Tuo,et al."Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of alpha-thioesters".Organic Chemistry Frontiers (2022).