南方科技大学知识苑(SUSTech KC): Iodine induced cyclization of sodium aminodiboranate: Reactivity and mechanisms investigation

题名	Iodine induced cyclization of sodium aminodiboranate: Reactivity and mechanisms investigation
作者	Li，Huizhen 1,2; Kang，Jia Xin 2; Ju，Mingyue 2; Wang，Zi Zhou 1; Liu，Zili 1; Wang，Jiahai 1; Xu，Cong Qiao3 ; He，Shan 1,4; Nag，Anindya 5,6
通讯作者	Li，Huizhen; Xu，Cong Qiao; He，Shan
发表日期	2022-09-15
DOI	10.1016/j.jorganchem.2022.122396
发表期刊	JOURNAL OF ORGANOMETALLIC CHEMISTRY 影响因子和分区
ISSN	0022-328X
EISSN	1872-8561
卷号	975
摘要	A new facile, cost-effective and highly efficient cyclization of sodium aminodiboranate induced by I is developed. The method can be used to prepare aminodiborane and its N–methyl/N, N–dimethyl derivatives, which is catalyst-free, performance independent of temperature and N–substituted groups. Theoretical calculations demonstrate that a two-step cyclization mechanism is favored in the cyclization of sodium aminodiboranate induced by I, where the intermolecular hydrogen bond and the (η-H) dihydrogen moiety play an important role, and the iodination of boron does not occur.
关键词	Aminodiborane Iodine Metal Boron–nitrogen–hydrogen Compound N, N-dimethyl Aminodiborane N-methyl Aminodiborane Sodium Aminodiboranate
相关链接	[Scopus记录]
收录类别	SCI ; EI
语种	英语
学校署名	通讯
资助项目	Basic and Applied Basic Research Foundation of Guangdong Province[2020A1515110282] ; National Natural Science Foundation of China[21601051] ; National Natural Science Foundation of China[22038002] ; National Natural Science Foundation of China[22103035] ; Deutsche Forschungsgemeinschaft[EXC 2050/1]
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear ; Chemistry, Organic
WOS记录号	WOS:000813011900006
出版者	ELSEVIER SCIENCE SA
EI入藏号	20222412225201
EI主题词	Boron ; Cost Effectiveness ; Cyclization ; Hydrogen Bonds ; Iodine ; Sodium Compounds
EI分类号	Nonferrous Metals And Alloys Excluding Alkali And Alkaline Earth Metals:549.3 ; Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Industrial Economics:911.2
ESI学科分类	CHEMISTRY
Scopus记录号	2-s2.0-85131716840
来源库	Scopus
引用统计	被引频次[WOS]：0
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/336203
专题	理学院_化学系
作者单位	1.School of Chemistry and Chemical Engineering,Guangzhou University,Guangzhou,510006,China 2.Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials,School of Chemistry and Chemical Engineering,Henan Normal University,Xinxiang,Henan,453007,China 3.Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China 4.Institute for Nano Scale and Technology,College of Science and Engineering,Flinders University,Bedford Park,Australia 5.Faculty of Electrical and Computer Engineering,Technische Universität Dresden,Dresden,01062,Germany 6.Centre for Tactile Internet with Human-in-the-Loop,Technische Universität Dresden,Dresden,01069,Germany
通讯作者单位	化学系
推荐引用方式 GB/T 7714	Li，Huizhen,Kang，Jia Xin,Ju，Mingyue,et al. Iodine induced cyclization of sodium aminodiboranate: Reactivity and mechanisms investigation[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2022,975.
APA	Li，Huizhen.,Kang，Jia Xin.,Ju，Mingyue.,Wang，Zi Zhou.,Liu，Zili.,...&Nag，Anindya.(2022).Iodine induced cyclization of sodium aminodiboranate: Reactivity and mechanisms investigation.JOURNAL OF ORGANOMETALLIC CHEMISTRY,975.
MLA	Li，Huizhen,et al."Iodine induced cyclization of sodium aminodiboranate: Reactivity and mechanisms investigation".JOURNAL OF ORGANOMETALLIC CHEMISTRY 975(2022).