南方科技大学知识苑(SUSTech KC): Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation

题名	Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation
作者	Yuan, Wei1,2 ; Zhu, Xujiang1,2 ; Xu, Yankun1,2 ; He, Chuan1,2
通讯作者	He, Chuan
发表日期	2022-06-01
DOI	10.1002/anie.202204912
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 影响因子和分区
ISSN	1433-7851
EISSN	1521-3773
卷号	61
摘要	Despite growing progress in the construction of chiral organosilicon compounds, the catalytic asymmetric synthesis of silicon-stereogenic silanols is less explored and remains a considerable challenge. Herein, we report the first enantioselective construction of silicon-stereogenic silanols by the catalytic asymmetric hydrolytic oxidation of dihydrosilanes. This practical procedure features ambient reaction conditions, high atom economy, good functional-group compatibility, and H-2 as the only by-product, and produces a wide range of valuable chiral silanols and bis-silanols in decent yields with excellent chemo- and stereoselectivity.
关键词	Asymmetric Catalysis Atom Economy Chiral Organosilanes Hydrolytic Oxidation Stereogenic Silanols
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
重要成果	NI论文
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China[21901104,22122102,22101120] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Shenzhen Science and Technology Innovation Committee[JCYJ20190809142809370] ; Stable Support Plan Program of Shenzhen Natural Science Fund[20200925152450004]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000813666100001
出版者	WILEY-V C H VERLAG GMBH
EI入藏号	20222512252091
EI主题词	Silicon ; Silicon compounds
EI分类号	Air Pollution Control:451.2 ; Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Chemical Agents and Basic Industrial Chemicals:803
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：36
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/347933
专题	深圳格拉布斯研究院理学院_化学系
作者单位	1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Guangdong, Peoples R China
第一作者单位	深圳格拉布斯研究院; 化学系
通讯作者单位	深圳格拉布斯研究院; 化学系
第一作者的第一单位	深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Yuan, Wei,Zhu, Xujiang,Xu, Yankun,et al. Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022,61.
APA	Yuan, Wei,Zhu, Xujiang,Xu, Yankun,&He, Chuan.(2022).Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,61.
MLA	Yuan, Wei,et al."Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 61(2022).