One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne

Huang, Fanping1,2,3; Yan, Zhewei1,2; Zheng, Xuejuan3; Cai, Yapeng1,2; Zhang, Hong1,2; Xia, Haiping1,2,3

2022-08-01

10.1002/chem.202201229

CHEMISTRY-A EUROPEAN JOURNAL   影响因子和分区

0947-6539

1521-3765

A novel one-pot reaction producing a metal vinylidene structure in a five-membered ring by cyclization of a multiyne has been achieved. The ring strain and the high stability of the cyclic metal vinylidene complexes have been analyzed experimentally and computationally. The metal vinylidene unit in a fused-ring complex is unreactive to both nucleophiles and electrophiles. It reacts however at the nearby carbonyl group achieving the unprecedented conversion of metal tributing factors for the aromaticity-driven process has been studied by DFT calculations.

aromaticity metallacycles metallapentalyne metal vinylidene

SCI ; EI

英语

通讯

National Natural Science Foundation of China["21931002","21871225","22171234"]

Chemistry

Chemistry, Multidisciplinary

WOS:000838162100001

WILEY-V C H VERLAG GMBH

20223312573810

Cyclization

Chemical Reactions:802.2

CHEMISTRY

Web of Science

1.Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
2.Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat iChEM, Xiamen 361005, Peoples R China
3.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China

Huang, Fanping,Yan, Zhewei,Zheng, Xuejuan,et al. One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne[J]. CHEMISTRY-A EUROPEAN JOURNAL,2022.

Huang, Fanping,Yan, Zhewei,Zheng, Xuejuan,Cai, Yapeng,Zhang, Hong,&Xia, Haiping.(2022).One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne.CHEMISTRY-A EUROPEAN JOURNAL.

Huang, Fanping,et al."One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne".CHEMISTRY-A EUROPEAN JOURNAL (2022).