南方科技大学知识苑(SUSTech KC): Visible Light-Induced Highly Regioselective and Stereoselective Oxysulfonylation of Alkynes for the Synthesis of (E)-beta-Phenoxy Vinylsulfones

题名	Visible Light-Induced Highly Regioselective and Stereoselective Oxysulfonylation of Alkynes for the Synthesis of (E)-beta-Phenoxy Vinylsulfones
作者	Xie, Wenjiao 1; Ma, Pengju 1; Zhang, Yujun 1; Xi, Longyi 1; Qiu, Shengqi 1,2; Huang, Xuan 1; Yang, Bo 1; Gao, Yuan 1; Zhang, Junmin 1
通讯作者	Huang, Xuan; Zhang, Junmin
发表日期	2022-08-01
DOI	10.1021/acs.orglett.2c02512
发表期刊	ORGANIC LETTERS 影响因子和分区
ISSN	1523-7060
EISSN	1523-7052
摘要	A highly efficient visible light-induced regioselective and stereoselective oxysulfonylation of alkynes with arylsulfonate phenol esters has been developed. This photocatalyst-and metal-free method proceeds smoothly under very mild conditions and exhibits a broad substrate scope, providing (E)-beta-phenoxy vinylsulfones in moderate to excellent yields. Mechanistic studies indicated the involvement of an electron donor- acceptor complex-mediated radical process.
相关链接	[来源记录]
收录类别	SCI
语种	英语
重要成果	NI论文
学校署名	非南科大
资助项目	National Natural Science Foundation of China["22171187","22001173"] ; Project of Department of Education of Guangdong Province[2020KTSCX116] ; Basic and Applied Research Foundation of Guangdong[2019A1515110906] ; Shenzhen Science and Technology Program["20200812202943001","GJHZ20210705141800003"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Principal Foundation of Shenzhen University[8570700000307]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000839416900001
出版者	AMER CHEMICAL SOC
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：13
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/382553
专题	南方科技大学
作者单位	1.Shenzhen Univ, Coll Chem & Environm Engn, Int Joint Res Ctr Mol Sci, Shenzhen 518060, Peoples R China 2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Xie, Wenjiao,Ma, Pengju,Zhang, Yujun,et al. Visible Light-Induced Highly Regioselective and Stereoselective Oxysulfonylation of Alkynes for the Synthesis of (E)-beta-Phenoxy Vinylsulfones[J]. ORGANIC LETTERS,2022.
APA	Xie, Wenjiao.,Ma, Pengju.,Zhang, Yujun.,Xi, Longyi.,Qiu, Shengqi.,...&Zhang, Junmin.(2022).Visible Light-Induced Highly Regioselective and Stereoselective Oxysulfonylation of Alkynes for the Synthesis of (E)-beta-Phenoxy Vinylsulfones.ORGANIC LETTERS.
MLA	Xie, Wenjiao,et al."Visible Light-Induced Highly Regioselective and Stereoselective Oxysulfonylation of Alkynes for the Synthesis of (E)-beta-Phenoxy Vinylsulfones".ORGANIC LETTERS (2022).