| 题名 | Free Aluminylenes: An Emerging Class of Compounds |
| 作者 | |
| 通讯作者 | Liu, Liu Leo |
| 发表日期 | 2022-09-01
|
| DOI | |
| 发表期刊 | |
| ISSN | 0947-6539
|
| EISSN | 1521-3765
|
| 摘要 | Aluminylenes (R-Al) are aluminium analogs of carbenes. In contrast to isolable carbenes, aluminylenes are extremely rare species. In the past years, pioneered by Schnockel, Roesky and Power, a few free aluminylenes and their complexes have been reported. Such compounds have the aluminium atom in the oxidation state +I, which contrasts with classical organoaluminium derivatives that contain the element in the +III oxidation state. Aluminylenes, either in their free state or in the coordination sphere of a Lewis base, are capable of coordinating to transition metals and activating inert chemical bonds. Free aluminylenes are emerging as potent synthetic platforms for unusual aluminium species. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 第一
; 通讯
|
| 资助项目 | National Natural Science Foundation of China[22101114]
; Guangdong Basic and Applied Basic Research Foundation[2022A1515011717]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
; China Postdoctoral Science Foundation (CPSF)["2021M691420","2022T150288"]
; CPSF[2022T150289]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
|
| WOS记录号 | WOS:000850668200001
|
| 出版者 | |
| EI入藏号 | 20223712727115
|
| EI主题词 | Aluminum
; Bond strength (chemical)
; Ligands
; Organic compounds
; Transition metals
|
| EI分类号 | Metallurgy and Metallography:531
; Aluminum:541.1
; Physical Chemistry:801.4
; Chemical Reactions:802.2
; Chemical Products Generally:804
; Organic Compounds:804.1
|
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：18
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/401517 |
| 专题 | 理学院_化学系 深圳格拉布斯研究院 |
| 作者单位 | 1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China |
| 第一作者单位 | 化学系; 深圳格拉布斯研究院; 南方科技大学 |
| 通讯作者单位 | 化学系; 深圳格拉布斯研究院; 南方科技大学 |
| 第一作者的第一单位 | 化学系; 深圳格拉布斯研究院 |
| 推荐引用方式 GB/T 7714 |
Zhang, Xin,Mei, Yanbo,Liu, Liu Leo. Free Aluminylenes: An Emerging Class of Compounds[J]. CHEMISTRY-A EUROPEAN JOURNAL,2022.
|
| APA |
Zhang, Xin,Mei, Yanbo,&Liu, Liu Leo.(2022).Free Aluminylenes: An Emerging Class of Compounds.CHEMISTRY-A EUROPEAN JOURNAL.
|
| MLA |
Zhang, Xin,et al."Free Aluminylenes: An Emerging Class of Compounds".CHEMISTRY-A EUROPEAN JOURNAL (2022).
|
| 条目包含的文件 | 条目无相关文件。 | |||||
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