南方科技大学知识苑(SUSTech KC): Synthesis of structurally diversified BINOLs and NOBINs via palladium-catalyzed C-H arylation with diazoquinones

题名	Synthesis of structurally diversified BINOLs and NOBINs via palladium-catalyzed C-H arylation with diazoquinones
作者	Ji-Wei Zhang1 ; Fei Jiang ; Ye-Hui Chen ; Shao-Hua Xiang3 ; Bin Tan
发表日期	2021
发表期刊	Science China-Chemistry 影响因子和分区
ISSN	1674-7291
卷号	64 期号:9页码:1515-1521
摘要	Privileged biaryl frameworks,BINOL and NOBIN,were efficiently constructed with sole 1-DNQs as arylation reagents under one set of reaction conditions.The judicious selection of palladium-catalytic system plays a pivotal role in the excellent selectivities.This transformation accommodated fairly broad substrate generality for both 2-naphthol and N-Boc-2-naphthy-lamine and afforded the structurally diversified BINOLs and NOBIN derivatives in high efficiency.Notably,the bromo-substituents which cannot survive in conventional palladium-catalyzed reactions were well-compatible with this set of condi-tions,providing an effective handle for further enriching the library of BINOLs and NOBINs.Preliminary attempts on the asymmetric variant of this reaction were also performed with up to 80:20 er for BINOLs synthesis.
相关链接	[万方记录]
语种	英语
学校署名	第一
来源库	WanFang
万方记录号	zgkx-eb202109012
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/401967
专题	理学院_化学系前沿与交叉科学研究院深圳格拉布斯研究院
作者单位	1.School of Chemistry and Chemical Engineering,Harbin Institute of Technology,Harbin 150001,China;Shenzhen Grubbs Institute and Department of Chemistry,Southern University of Science and Technology,Shenzhen 518055,China 2.Shenzhen Grubbs Institute and Department of Chemistry,Southern University of Science and Technology,Shenzhen 518055,China 3.Shenzhen Grubbs Institute and Department of Chemistry,Southern University of Science and Technology,Shenzhen 518055,China;Academy for Advanced Interdisciplinary Studies,Southern University of Science and Technology,Shenzhen 518055,China
第一作者单位	化学系; 深圳格拉布斯研究院
第一作者的第一单位	化学系; 深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Ji-Wei Zhang,Fei Jiang,Ye-Hui Chen,et al. Synthesis of structurally diversified BINOLs and NOBINs via palladium-catalyzed C-H arylation with diazoquinones[J]. Science China-Chemistry,2021,64(9):1515-1521.
APA	Ji-Wei Zhang,Fei Jiang,Ye-Hui Chen,Shao-Hua Xiang,&Bin Tan.(2021).Synthesis of structurally diversified BINOLs and NOBINs via palladium-catalyzed C-H arylation with diazoquinones.Science China-Chemistry,64(9),1515-1521.
MLA	Ji-Wei Zhang,et al."Synthesis of structurally diversified BINOLs and NOBINs via palladium-catalyzed C-H arylation with diazoquinones".Science China-Chemistry 64.9(2021):1515-1521.