南方科技大学知识苑(SUSTech KC): Reactivity Studies of a Hydroxy-Substituted Irida-carbolong Complex

题名	Reactivity Studies of a Hydroxy-Substituted Irida-carbolong Complex
作者	Li, Jinhua1,2 ; Chu, Zhenwei1,2,3 ; Lu, Zhengyu1,2 ; Luo, Ming1,2 ; Chen, Dafa1,2 ; Xia, Haiping1,2,3
通讯作者	Chen, Dafa; Xia, Haiping
发表日期	2022-09-01
DOI	10.1021/acs.organomet.2c00306
发表期刊	ORGANOMETALLICS 影响因子和分区
ISSN	0276-7333
EISSN	1520-6041
摘要	The reactivities of the aromatic beta-hydroxy-sub-stituted irida-carbolong complex [Ir{=CHC(CH2C-(CO2Me)(2)CH2)=CC=CHC(OH)=CH}(CO)(PPh3)(2)]BF4 (1) with a series of reagents, including AcCl, (CF3CO)(2)O, NaOH, Et2NSF3 and NaNO2/HBF4 center dot H2O, were studied, affording five new complexes [Ir{=CHC(CH2C(CO2Me)(2)CH2)=CC=CHC-(OCOCH3)=CH}(CO)(PPh3)(2)]BF4 (2), [Ir{=CHC(CH2C- (CO2Me)2CH(2))=CC=CHC(OCOCF3)=CH}(CO)(PPh3)(2)]-BF4 (3) , [Ir{CH=C(CH2C(CO2Me)(2)CH=)CC=CHC(O)-CH2}(CO)(PPh3)(2)] (4) , [Ir{=CHC(CH2C(CO2Me)(2)CH2)= CC=CHC(F)=CH}(CO)(PPh3)(2)]BF4 (5) , and [Ir{C(O)C- (CH2C(CO2Me)(2)CH2)=CC=CHC(O)CH=N(OH)}(NO2)-(PPh3)(2)] (6), in the yields of 61-87%, respectively. Each of complexes 2, 3 and 5 sti l l contains an iridapentalene fragment. In contrast, the [5,5]-fused iridabic y c l e in complex 4 is dearomatized, and the alteration of the metallabic y c l e skeleton was involved during the preparation of 6, with the transformation from a [5,5]-fused iridabicycle to a ring-expansion [5,6]-fused iridabicycle.
相关链接	[来源记录]
收录类别	SCI
语种	英语
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China["22071098","21871068","22101123","22101115"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Shenzhen Science and Technology Innovation Committee["JCYJ20200109140812302","JCYJ20210324105013035"]
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear ; Chemistry, Organic
WOS记录号	WOS:000855906600001
出版者	AMER CHEMICAL SOC
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：0
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/402379
专题	理学院_化学系深圳格拉布斯研究院
作者单位	1.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China
第一作者单位	化学系; 深圳格拉布斯研究院
通讯作者单位	化学系; 深圳格拉布斯研究院
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Li, Jinhua,Chu, Zhenwei,Lu, Zhengyu,et al. Reactivity Studies of a Hydroxy-Substituted Irida-carbolong Complex[J]. ORGANOMETALLICS,2022.
APA	Li, Jinhua,Chu, Zhenwei,Lu, Zhengyu,Luo, Ming,Chen, Dafa,&Xia, Haiping.(2022).Reactivity Studies of a Hydroxy-Substituted Irida-carbolong Complex.ORGANOMETALLICS.
MLA	Li, Jinhua,et al."Reactivity Studies of a Hydroxy-Substituted Irida-carbolong Complex".ORGANOMETALLICS (2022).