Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Azoarenes to Hydrazoarenes with Ethanol

Gong，Dawei1; Kong，Degong2; Xu，Na1; Hua，Yuhui2; Liu，Bo1; Xu，Zhanlin1

2022

10.1021/acs.orglett.2c02866

ORGANIC LETTERS   影响因子和分区

1523-7060

1523-7052

The transfer hydrogenation of azoarenes to hydrazoarenes using ethanol as a hydrogen source by a bidentate Ru(II)-NC complex is developed. A weak base is crucial for this semihydrogenation that can efficiently avoid hydrazoarene dehydrogenation under strongly basic conditions. Control experiments and density functional theory calculations demonstrate the mechanism via a Meerwein-Ponndorf-Verley mechanism, and the only byproduct is ethyl acetate. This study offers a new and simple approach for the synthesis of hydrazoarenes.

SCI

英语

NI论文

其他

[YDZJ202201ZYTS617] ; [20210101117JC] ; [JJKH20220430KJ]

Chemistry

Chemistry, Organic

WOS:000872606700001

AMER CHEMICAL SOC

CHEMISTRY

2-s2.0-85139450499

Scopus

1.Key Lab. of Preparation and Application of Environmental Friendly Materials,Ministry of Education,College of Chemistry,Jilin Normal University,Changchun,130103,China
2.Shenzhen Grubbs Institute,Department of Chemistry,Southern University of Science and Technology,Shenzhen,518000,China

Gong，Dawei,Kong，Degong,Xu，Na,et al. Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Azoarenes to Hydrazoarenes with Ethanol[J]. ORGANIC LETTERS,2022,24(40).

Gong，Dawei,Kong，Degong,Xu，Na,Hua，Yuhui,Liu，Bo,&Xu，Zhanlin.(2022).Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Azoarenes to Hydrazoarenes with Ethanol.ORGANIC LETTERS,24(40).

Gong，Dawei,et al."Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Azoarenes to Hydrazoarenes with Ethanol".ORGANIC LETTERS 24.40(2022).