Experimental optimization analysis on operating conditions of CO removal process from hydrogen-rich reformate

Xing，Shuang1; Su，Huaming2; Yang，Meng2; Gong，Hongwei3; Ban，Shuai2; Zhao，Chen4; Wang，Haijiang1

2022

10.1016/j.ijhydene.2022.08.228

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY   影响因子和分区

0360-3199

1879-3487

The catalytic effects of CO preferential oxidation and methanation catalysts for deep CO removal under different operating conditions (temperature, space velocity, water content, etc.) are systematically studied from the aspects of CO content, CO selectivity, and hydrogen loss index. Results indicate that the 3 wt% Ru/AlO preferential oxidation catalysts reduce CO content to below 10 ppm with a high hydrogen consumption of 11.6–15.7%. And methanation catalysts with 0.7 wt% Ru/AlO also exhibit excellent CO removal performance at 220–240 °C without hydrogen loss. Besides, NiCl/CeO methanation catalysts possess the characteristics of high space velocity, high activity, and high water-gas resistance, and can maintain the CO content at close to 20 ppm. Based on these experimental results, the coupling scheme of combining NiCl/CeO methanation catalysts (low cost and high reaction space velocity) with 0.7 wt% Ru/AlO methanation catalysts (high activity) to reduce CO content to below10 ppm is proposed.

CO content Hydrogen Methanation Preferential oxidation Selectivity

SCI ; EI

英语

第一 ; 通讯

National Key Research and Development Program of China[2018YFB1502503];

Chemistry ; Electrochemistry ; Energy & Fuels

Chemistry, Physical ; Electrochemistry ; Energy & Fuels

WOS:001048701900001

PERGAMON-ELSEVIER SCIENCE LTD

20224112857315

Aluminum compounds ; Catalyst activity ; Catalyst selectivity ; Catalytic oxidation ; Chlorine compounds ; Hydrogenation ; Methanation ; Nickel compounds ; Ruthenium compounds

Air Pollution Control:451.2 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804

ENGINEERING

2-s2.0-85139218053

Scopus

1.Department of Mechanical and Energy Engineering,Southern University of Science and Technology,Shenzhen,518055,China
2.Department of New Energy and Materials,China University of Petroleum (Beijing),Beijing,102249,China
3.CNOOC EnerTech-Drilling & Production Co. Shenzhen Branch,Shenzhen,518055,China
4.Department of New Energy Vehicle Technology,Shenzhen Polytechnic,Shenzhen,518055,China

Xing，Shuang,Su，Huaming,Yang，Meng,et al. Experimental optimization analysis on operating conditions of CO removal process from hydrogen-rich reformate[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2022,48(64):25216-25230.

Xing，Shuang.,Su，Huaming.,Yang，Meng.,Gong，Hongwei.,Ban，Shuai.,...&Wang，Haijiang.(2022).Experimental optimization analysis on operating conditions of CO removal process from hydrogen-rich reformate.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,48(64),25216-25230.

Xing，Shuang,et al."Experimental optimization analysis on operating conditions of CO removal process from hydrogen-rich reformate".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 48.64(2022):25216-25230.