南方科技大学知识苑(SUSTech KC): Palladium catalyzed decarboxylative beta-C-glycosylation of glycals with oxazol-5-(4H)-ones as acceptors

题名	Palladium catalyzed decarboxylative beta-C-glycosylation of glycals with oxazol-5-(4H)-ones as acceptors
作者	Ding, Wei-Yi1,2 ; Liu, Huan-Huan 1,2 ; Cheng, Jun Kee1,2 ; Yao, Hui 3; Xiang, Shao-Hua1,2 ; Tan, Bin1,2
通讯作者	Yao, Hui; Xiang, Shao-Hua
发表日期	2022-10-01
DOI	10.1039/d2qo01308h
发表期刊	Organic Chemistry Frontiers 影响因子和分区
ISSN	2052-4129
摘要	Despite the increased importance of C-glycosides in biochemistry, the strategy for creating the C-glycosidic bond stereoselectively has received less attention than that for its O- and N-counterparts. We describe here a beta-C-glycosylation of oxazol-5(4H)-ones which are the direct precursors of amino acids. For a wide variety of glycal donors and glycosyl acceptors, this chemistry could be accomplished with excellent efficiency and exquisite chemoselectivity without exogenous bases in most cases. The excellent stereocontrol at the anomeric center originates from the steric hindrance imposed by the bulky phosphine ligand.
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	第一 ; 通讯
资助项目	Shenzhen Special Funds[JCYJ20180305123508258]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000866135000001
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20224513055932
EI主题词	Ligands ; Palladium ; Phosphorus compounds
EI分类号	Biology:461.9 ; Precious Metals:547.1 ; Biochemistry:801.2 ; Physical Chemistry:801.4
来源库	Web of Science
引用统计	被引频次[WOS]：11
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/406550
专题	深圳格拉布斯研究院理学院_化学系
作者单位	1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 3.China Three Gorges Univ, Coll Biol & Pharmaceut Sci, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Peoples R China
第一作者单位	深圳格拉布斯研究院; 化学系
通讯作者单位	深圳格拉布斯研究院; 化学系
第一作者的第一单位	深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Ding, Wei-Yi,Liu, Huan-Huan,Cheng, Jun Kee,et al. Palladium catalyzed decarboxylative beta-C-glycosylation of glycals with oxazol-5-(4H)-ones as acceptors[J]. Organic Chemistry Frontiers,2022.
APA	Ding, Wei-Yi,Liu, Huan-Huan,Cheng, Jun Kee,Yao, Hui,Xiang, Shao-Hua,&Tan, Bin.(2022).Palladium catalyzed decarboxylative beta-C-glycosylation of glycals with oxazol-5-(4H)-ones as acceptors.Organic Chemistry Frontiers.
MLA	Ding, Wei-Yi,et al."Palladium catalyzed decarboxylative beta-C-glycosylation of glycals with oxazol-5-(4H)-ones as acceptors".Organic Chemistry Frontiers (2022).