Enhanced Catalytic Performance in Two-Electron Oxygen Reduction Reaction via ZnSnO3Perovskite

Qian，Junning1; Liu，Wei2; Jiang，Yuting1; Mu，Yongbiao1; Cai，Yuanyuan1; Shi，Le2; Zeng，Lin1

2022

10.1021/acssuschemeng.2c04965

ACS Sustainable Chemistry & Engineering   影响因子和分区

2168-0485

2168-0485

Effective design of high-performance electrocatalysts for the green synthesis of hydrogen peroxide (H2O2) by a two-electron oxygen reduction reaction (2e-ORR) method is of vital importance in various applications, but it is still a great challenge for the electrocatalysis community after all of these years. In this work, a novel ZnSnO3 perovskite is prepared as a highly selective and stable catalyst for the electrosynthesis of H2O2 via 2e-ORR. Profiting from its perovskite-type structure, it presents excellent electrochemical activity toward 2e-ORR in an alkaline electrolyte, and correlated H2O2 selectivity can reach 76%. Additionally, the H2O2 selectivity of ZnSnO3 perovskite in 2e-ORR can be steadily maintained for 6 h in a durability test, and the production of H2O2 synthesis achieves a total amount of 78 mmol·gcat-1·h-1 at 0.1 V. Impressively, ZnSnO3 perovskite delivers a preferable turnover frequency (TOF) of 1.31 × 10-3 s-1 compared to the commercial Pt/C catalyst (0.05 × 10-3 s-1) under the same conditions, demonstrating the great applicable potential of ZnSnO3 perovskite as an active non-noble metal oxide electrocatalyst for 2e-ORR. From the view of catalytic essence, the high electrochemical performance of ZnSnO3 perovskite in 2e-ORR originates from the suitable adsorption capacity on its surface for the adsorption of important *OOH intermediates according to the theoretical calculations. Therefore, ZnSnO3 perovskite as the efficient 2e-ORR catalyst is a promising candidate for the green synthesis of hydrogen peroxide.

Green synthesis Hydrogen peroxide Oxygen reduction reaction Perovskite ZnSnO3

SCI

英语

第一 ; 通讯

[JCYJ20200109141216566] ; [2021A1515010412]

Chemistry ; Science & Technology - Other Topics ; Engineering

Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical

WOS:000877239900001

AMER CHEMICAL SOC

2-s2.0-85140617492

Scopus

1.Department of Mechanical and Energy Engineering,Southern University of Science and Technology,Shenzhen,518055,China
2.State Key Laboratory of Electrical Insulation and Power Equipment,Center of Nanomaterials for Renewable Energy,School of Electrical Engineering,Xi'An Jiaotong University,Xi'an,710049,China

Qian，Junning,Liu，Wei,Jiang，Yuting,et al. Enhanced Catalytic Performance in Two-Electron Oxygen Reduction Reaction via ZnSnO3Perovskite[J]. ACS Sustainable Chemistry & Engineering,2022.

Qian，Junning.,Liu，Wei.,Jiang，Yuting.,Mu，Yongbiao.,Cai，Yuanyuan.,...&Zeng，Lin.(2022).Enhanced Catalytic Performance in Two-Electron Oxygen Reduction Reaction via ZnSnO3Perovskite.ACS Sustainable Chemistry & Engineering.

Qian，Junning,et al."Enhanced Catalytic Performance in Two-Electron Oxygen Reduction Reaction via ZnSnO3Perovskite".ACS Sustainable Chemistry & Engineering (2022).