Structural disorder induced enhanced gas-sensing performance of ZnO with surface amorphous layer

Ma，Zhenyu1,2; Deng，Yong3; Luo，Kaiyi1; Wang，Xiaoyi2; Qiu，Yang3; Chen，Longqing1

2023

10.1016/j.vacuum.2022.111638

VACUUM   影响因子和分区

0042-207X

The development of highly sensitive gas sensors is of great significance to the environment and human health. In this work, we demonstrate the enhancement of the gas-sensing performance of ZnO via employing disorder surface. The random arrangement of surface atoms could give rise to a coarse surface for improving gas adsorption. Moreover, due to the absence of carrier diffusion in amorphous layer, the Anderson localization could restrict the carrier interaction. Most crucially, the electron localization led by lattice disorder significantly elevate the gas monitoring sensitivity. As a result, the acetone sensitivity of ZnO is greatly enhanced (up to ∼ 20.8 times compared with the pristine sample). This work theoretically and experimentally investigate the role of surface disorder in enhancing gas-sensing performance, and also present a mild, low-cost method to modify the material for further applications.

Gas-sensing Lattice disorder Surface specific area ZnO nanoparticles

SCI ; EI

英语

通讯

Department of Science and Technology of Sichuan Province[2021YFH0174];Department of Science and Technology of Sichuan Province[2022YFG0102];

WOS:000883322500006

20224513071939

Acetone ; Chemical detection ; Chemical sensors ; Gas adsorption ; Gas detectors ; Gas sensing electrodes ; Gases ; II-VI semiconductors

Semiconducting Materials:712.1 ; Nanotechnology:761 ; Chemistry:801 ; Chemical Operations:802.3 ; Organic Compounds:804.1 ; Accidents and Accident Prevention:914.1 ; Special Purpose Instruments:943.3

MATERIALS SCIENCE

2-s2.0-85141262993

Scopus

1.Key Laboratory of Radiation Physics and Technology of Ministry of Education,Institute of Nuclear Science and Technology,Sichuan University,Chengdu,610064,China
2.Southwest Minzu University,State Ethnic Affairs Commission,Chengdu,610041,China
3.Pico Center,SUSTech Core Research Facilities,Southern University of Science and Technology,Shenzhen,518055,China

Ma，Zhenyu,Deng，Yong,Luo，Kaiyi,et al. Structural disorder induced enhanced gas-sensing performance of ZnO with surface amorphous layer[J]. VACUUM,2023,207.

Ma，Zhenyu,Deng，Yong,Luo，Kaiyi,Wang，Xiaoyi,Qiu，Yang,&Chen，Longqing.(2023).Structural disorder induced enhanced gas-sensing performance of ZnO with surface amorphous layer.VACUUM,207.

Ma，Zhenyu,et al."Structural disorder induced enhanced gas-sensing performance of ZnO with surface amorphous layer".VACUUM 207(2023).