| 题名 | Developing Ru-Catalysts for Asymmetric Transfer Hydrogenation of Acyclic Imines |
| 作者 | |
| 通讯作者 | Xu, Chen; Xing, Xiangyou |
| 发表日期 | 2022-11-18
|
| DOI | |
| 发表期刊 | |
| ISSN | 1523-7060
|
| EISSN | 1523-7052
|
| 卷号 | 24期号:45页码:8354-8358 |
| 摘要 | Asymmetric transfer hydrogenation (ATH) of acyclic imines has been rarely reported by using Ru-based catalysts. In this manuscript, employing Ru-catalysts with minimal stereo-genicity in combination with formic acid/triethylamine as the hydrogen donor enables a highly efficient ATH of N-diphenylphosphinyl acyclic imines. These substrates that include various aryl alkyl and heteroaryl alkyl substituted imines were all compatible with this catalytic system, and the corresponding reduced amines were obtained with excellent enantiomeric excess (ee's) and yields. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI论文
|
| 学校署名 | 通讯
|
| 资助项目 | Shenzhen Nobel Prize Scientists Laboratory Project[C17783101]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
; Natural Science Foundation of Guangdong Province[2021A1515010329]
; National Natural Science Foundation of China[K21211026]
; Shenzhen Science and Technology Program[
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| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Organic
|
| WOS记录号 | WOS:000884878200001
|
| 出版者 | |
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
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| 引用统计 |
被引频次[WOS]：2
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/412179 |
| 专题 | 深圳格拉布斯研究院 理学院_化学系 |
| 作者单位 | 1.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China |
| 第一作者单位 | 深圳格拉布斯研究院; 化学系 |
| 通讯作者单位 | 深圳格拉布斯研究院; 化学系 |
| 推荐引用方式 GB/T 7714 |
He, Dongxu,Xu, Chen,Xing, Xiangyou. Developing Ru-Catalysts for Asymmetric Transfer Hydrogenation of Acyclic Imines[J]. ORGANIC LETTERS,2022,24(45):8354-8358.
|
| APA |
He, Dongxu,Xu, Chen,&Xing, Xiangyou.(2022).Developing Ru-Catalysts for Asymmetric Transfer Hydrogenation of Acyclic Imines.ORGANIC LETTERS,24(45),8354-8358.
|
| MLA |
He, Dongxu,et al."Developing Ru-Catalysts for Asymmetric Transfer Hydrogenation of Acyclic Imines".ORGANIC LETTERS 24.45(2022):8354-8358.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| 17.acs.orglett.2c033（1884KB） | -- | -- | 限制开放 | -- | ||
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