南方科技大学知识苑(SUSTech KC): Asymmetric organocatalytic (3 + 2) annulation of propargylic alcohols with indolylnaphthalenols: synergistic construction of axial and central chirality

题名	Asymmetric organocatalytic (3 + 2) annulation of propargylic alcohols with indolylnaphthalenols: synergistic construction of axial and central chirality
作者	Xia，Yan 1; Liu，Meiwen2 ; Qian，Chenxiao2 ; Li，Pengfei2 ; Dong，Mingxin 1; Li，Wenjun 1
通讯作者	Li，Pengfei; Dong，Mingxin; Li，Wenjun
发表日期	2022-11-14
DOI	10.1039/d2qo01625g
发表期刊	Organic Chemistry Frontiers 影响因子和分区
ISSN	2052-4110
EISSN	2052-4129
卷号	2023 期号:10页码:30-34
摘要	Organocatalytic enantioselective construction of chiral spiro N,N-acetal carbon stereocenters and axially chiral 3-arylindoles has been achieved via a chiral phosphoric acid (CPA)-catalyzed (3 + 2) annulation of α-(3-isoindolinonyl) propargylic alcohols with 1-(3-indolyl)naphthalen-2-ols, affording a broad scope of pyrrolo[1,2-a]indoles bearing both enantioenriched spiro isoindolinone-indoline and atropisomeric naphthalenol frameworks. Based on control experiments and our previous work, a possible mechanism was proposed accordingly.
相关链接	[Scopus记录]
收录类别	SCI
语种	英语
学校署名	通讯
资助项目	[ZR2021MB026] ; [tsqn201812047] ; [20200925151614002] ; [2020B121201002]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000885655000001
出版者	ROYAL SOC CHEMISTRY
Scopus记录号	2-s2.0-85142453396
来源库	Scopus
引用统计	被引频次[WOS]：17
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/415757
专题	理学院_化学系理学院深圳格拉布斯研究院
作者单位	1.Department of Medicinal Chemistry,School of Pharmacy,Qingdao University,Qingdao,Shandong,266021,China 2.Shenzhen Grubbs Institute and Department of Chemistry,Guangdong Provincial Key Laboratory of Catalysis,College of Science,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
通讯作者单位	化学系; 深圳格拉布斯研究院; 理学院
推荐引用方式 GB/T 7714	Xia，Yan,Liu，Meiwen,Qian，Chenxiao,et al. Asymmetric organocatalytic (3 + 2) annulation of propargylic alcohols with indolylnaphthalenols: synergistic construction of axial and central chirality[J]. Organic Chemistry Frontiers,2022,2023(10):30-34.
APA	Xia，Yan,Liu，Meiwen,Qian，Chenxiao,Li，Pengfei,Dong，Mingxin,&Li，Wenjun.(2022).Asymmetric organocatalytic (3 + 2) annulation of propargylic alcohols with indolylnaphthalenols: synergistic construction of axial and central chirality.Organic Chemistry Frontiers,2023(10),30-34.
MLA	Xia，Yan,et al."Asymmetric organocatalytic (3 + 2) annulation of propargylic alcohols with indolylnaphthalenols: synergistic construction of axial and central chirality".Organic Chemistry Frontiers 2023.10(2022):30-34.