南方科技大学知识苑(SUSTech KC): The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers

题名	The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers
作者	Xiang, Shao-Hua1,2,3 ; Cheng, Jun Kee1 ; Tan, Bin1
通讯作者	Tan, Bin
发表日期	2022-11-01
DOI	10.1055/a-1965-2928
发表期刊	SYNLETT 影响因子和分区
ISSN	0936-5214
EISSN	1437-2096
卷号	33 期号:20
摘要	The venerable axially chiral biaryl skeletons used widely in asymmetric catalysis such as BINOLs, NOBINs, QUINOLs, and CPAs possess a 2-naphthol moiety or are derived from the naphthol precursor. The hydroxy functionality offers the interaction point or serves as functional handle for synthetic elaboration. This prevalence and significance drive our studies to incorporate this nucleophile class to fabricate an assortment of atropisomers. By activating the reacting partners via distinctive mechanisms, the arylation of quinones, azo-or nitroso-naphthalenes, VQM intermediates, 1,2,4-triazole-3,5-diones, isoquinolines, and 1-bromo-2-naphthols with 2-naphthols were successfully attained. A concise account of these developments is provided in this article. 1 Introduction 2 Asymmetric Arylation with Quinones 3 Asymmetric Arylation with Electron-Deficient Arenes 4 Asymmetric Synthesis of Atropisomers with other Electrophiles 5 Conclusion
关键词	atropisomers 2-naphthols asymmetric synthesis organocatalysis arylation quinones election-deficient arenes
相关链接	[来源记录]
收录类别	SCI
语种	英语
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China[2021YFF0701604] ; Guangdong Innovative Program["22271135","22231004"] ; Shenzhen Special Funds[2019BT02Y335] ; [JCYJ20210324120205016] ; [JCYJ20210324105005015]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000890891700005
出版者	GEORG THIEME VERLAG KG
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：5
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/417049
专题	理学院_化学系前沿与交叉科学研究院深圳格拉布斯研究院
作者单位	1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China
第一作者单位	化学系; 深圳格拉布斯研究院; 前沿与交叉科学研究院
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Xiang, Shao-Hua,Cheng, Jun Kee,Tan, Bin. The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers[J]. SYNLETT,2022,33(20).
APA	Xiang, Shao-Hua,Cheng, Jun Kee,&Tan, Bin.(2022).The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers.SYNLETT,33(20).
MLA	Xiang, Shao-Hua,et al."The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers".SYNLETT 33.20(2022).