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题名

Examining the implications of photochemical indicators for O-3-NOx-VOC sensitivity and control strategies: a case study in theYangtze River Delta (YRD), China

作者
通讯作者Qin, Momei; Hu, Jianlin
发表日期
2022-11-22
DOI
发表期刊
ISSN
1680-7316
EISSN
1680-7324
卷号22期号:22
摘要
Ozone (O-3) has become a significant air pollutant in China in recent years. O-3 abatement is challenging due to the nonlinear response of O-3 to precursors nitrogen oxides (NOx) and volatile organic compounds (VOCs). Photochemical indicators are widely used to estimate the O-3-NOx-VOC sensitivity, and this has important policy implications. However, the effectiveness of the indicators has seldom been evaluated. This study examined the applications of four indicators that include the ratio of the production rates of H2O2 and HNO3 (PH2O2/PHNO3), HCHO/NO2, HCHO/NOy, and reactive nitrogen (NOy) in the Yangtze River Delta (YRD) with localized thresholds. The overall accuracy was high (> 92%) for all indicators and not significantly reduced with different simulation periods or in different locations of the region. By comparing with the O-3 isopleths, it was found that HCHO/NO(2 )and HCHO/NOy showed the most consistency, whereas PH2O2/PHNO3 (NOy) tended to underestimate (overestimate) the positive response of O-3 to NOx. Additionally, PH2O2/PHNO3 was less likely to attribute the O-3 formation to mixed sensitivity than the other indicators, and this demonstrated a preference for a single-pollutant control strategy. This study also revealed that the details in the methodology used to derive the threshold values impacted the results, and this may produce uncertainties in the application of photochemical indicators.
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收录类别
语种
英语
学校署名
其他
资助项目
[BK20200815] ; [42107117] ; [42007187] ; [42021004]
WOS研究方向
Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences
WOS类目
Environmental Sciences ; Meteorology & Atmospheric Sciences
WOS记录号
WOS:000890249400001
出版者
ESI学科分类
GEOSCIENCES
来源库
Web of Science
引用统计
被引频次[WOS]:16
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/417065
专题工学院_环境科学与工程学院
作者单位
1.Nanjing Univ Informat Sci & Technol, Collaborat Innovat Ctr Atmospher Environm & Equipm, Jiangsu Key Lab Atmospher Environm Monitoring & Po, Nanjing 210044, Peoples R China
2.Southern Univ Sci & Technol, Sch Environm Sci & Engn, Shenzhen 518055, Peoples R China
推荐引用方式
GB/T 7714
Li, Xun,Qin, Momei,Li, Lin,et al. Examining the implications of photochemical indicators for O-3-NOx-VOC sensitivity and control strategies: a case study in theYangtze River Delta (YRD), China[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2022,22(22).
APA
Li, Xun.,Qin, Momei.,Li, Lin.,Gong, Kangjia.,Shen, Huizhong.,...&Hu, Jianlin.(2022).Examining the implications of photochemical indicators for O-3-NOx-VOC sensitivity and control strategies: a case study in theYangtze River Delta (YRD), China.ATMOSPHERIC CHEMISTRY AND PHYSICS,22(22).
MLA
Li, Xun,et al."Examining the implications of photochemical indicators for O-3-NOx-VOC sensitivity and control strategies: a case study in theYangtze River Delta (YRD), China".ATMOSPHERIC CHEMISTRY AND PHYSICS 22.22(2022).
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