Integration of Milstein Ru-PNN and Rh-Tribi/Tetrabi for Isomerization Linear Selective Hydroformylation of Far Internal Alkenes

Zhang, Runtong1,2; Yan, Xin1,2; Chen, Caiyou1,2; Duan, Ya-Nan3; He, Xintong3,4; Bai, Shao-Tao5,6; Zhang, Xumu1,2

2022-12-01

10.1021/acs.joc.2c02423

JOURNAL OF ORGANIC CHEMISTRY   影响因子和分区

0022-3263

1520-6904

Converting cheap and abundant internal alkenes to value-added linear aldehydes is of great importance but not an addressed issue. In this paper, an integration of a Milstein-type Ru-PNN catalyst and our Rh- Tribi/Tetrabi catalyst was first demonstrated in highly improved isomerization linear selective hydroformylation of 2-, 3-, and 4-alkenes, yielding excellent linear selectivities and activities (linear selectivity improvements of 2.2-58%, up to 94.2-98.6%, and turnover numbers improvements of 61-335 TON, up to 385-851) compared to the Ru- PNN/Rh-Bisbi system.

SCI

英语

第一 ; 通讯

Guangdong Basic and Applied Basic Research Foundation[2021A1515110808] ; National Key R&D Program of China["2021YFA1500201","2021YFA0910800"] ; Chemistry and Chemical Engineering Guangdong Laboratory[2132013] ; National Natural Science Foundation of China[21991113]

Chemistry

Chemistry, Organic

WOS:000893952000001

AMER CHEMICAL SOC

CHEMISTRY

Web of Science

1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China
3.Chem & Chem Engn Guangdong Lab, Shantou 515031, Peoples R China
4.Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong 999077, Peoples R China
5.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China
6.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China

Zhang, Runtong,Yan, Xin,Chen, Caiyou,et al. Integration of Milstein Ru-PNN and Rh-Tribi/Tetrabi for Isomerization Linear Selective Hydroformylation of Far Internal Alkenes[J]. JOURNAL OF ORGANIC CHEMISTRY,2022.

Zhang, Runtong.,Yan, Xin.,Chen, Caiyou.,Duan, Ya-Nan.,He, Xintong.,...&Zhang, Xumu.(2022).Integration of Milstein Ru-PNN and Rh-Tribi/Tetrabi for Isomerization Linear Selective Hydroformylation of Far Internal Alkenes.JOURNAL OF ORGANIC CHEMISTRY.

Zhang, Runtong,et al."Integration of Milstein Ru-PNN and Rh-Tribi/Tetrabi for Isomerization Linear Selective Hydroformylation of Far Internal Alkenes".JOURNAL OF ORGANIC CHEMISTRY (2022).