| 题名 | Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene-Phosphines |
| 作者 | |
| 通讯作者 | Yang, Limin; Tan, Bin; Wang, Jun (Joelle) |
| 发表日期 | 2023-01-16
|
| DOI | |
| 发表期刊 | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| 卷号 | 62期号:3 |
| 摘要 | A Cu/CPA co-catalytic system has been developed for achieving the direct hydrophosphinylation of alkynes with phosphine oxides in delivering novel axially chiral phosphorus-containing alkenes in high yields and excellent enantioselectivities (up to 99 % yield and 99 % ee). DFT calculations were performed to elucidate the reaction pathway and the origin of enantiocontrol. This streamlined and modular methodology establishes a new platform for the design and application of new axially chiral styrene-phosphine ligands. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI论文
|
| 学校署名 | 第一
; 通讯
|
| 资助项目 | [GRF 12301821]
; [21971102]
; [22231004]
; [21825105]
; [22271071]
; [2020B121201002]
; [2019BT02Y335]
; [KQTD20210811090112004]
; [LY20B020010]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
|
| WOS记录号 | WOS:000896830800001
|
| 出版者 | |
| EI入藏号 | 20225013252230
|
| EI主题词 | Copper
; Design For Testability
; Hydrocarbons
; Ligands
; Phosphoric Acid
; Phosphorus Compounds
|
| EI分类号 | Copper:544.1
; Physical Chemistry:801.4
; Organic Compounds:804.1
; Inorganic Compounds:804.2
|
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：53
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/417122 |
| 专题 | 理学院_化学系 深圳格拉布斯研究院 |
| 作者单位 | 1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 3.Hong Kong Baptist Univ, Dept Chem, Hong Kong, Peoples R China 4.Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 311121, Peoples R China |
| 第一作者单位 | 化学系; 深圳格拉布斯研究院; 南方科技大学 |
| 通讯作者单位 | 化学系; 深圳格拉布斯研究院; 南方科技大学 |
| 第一作者的第一单位 | 化学系; 深圳格拉布斯研究院 |
| 推荐引用方式 GB/T 7714 |
Cai, Baohua,Cui, Yuan,Zhou, Jian,et al. Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene-Phosphines[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2023,62(3).
|
| APA |
Cai, Baohua.,Cui, Yuan.,Zhou, Jian.,Wang, Yong-Bin.,Yang, Limin.,...&Wang, Jun .(2023).Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene-Phosphines.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,62(3).
|
| MLA |
Cai, Baohua,et al."Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene-Phosphines".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 62.3(2023).
|
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| Angew Chem Int Ed - （7414KB） | -- | -- | 限制开放 | -- | ||
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