南方科技大学知识苑(SUSTech KC): Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3)

题名	Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3)
作者	Tan, Jingjie 1; Hu, Chaopeng2,3 ; Yang, Xin 1; Ju, Shaoying 1; Cao, Levy L.4; Wu, Yile 1; Liu, Liu Leo2,3 ; Stephan, Douglas W.1,4
通讯作者	Wu, Yile; Liu, Liu Leo; Stephan, Douglas W.
发表日期	2023-01-03
DOI	10.1039/d2cc06075b
发表期刊	CHEMICAL COMMUNICATIONS 影响因子和分区
ISSN	1359-7345
EISSN	1364-548X
卷号	59 期号:3
摘要	The aluminum analogue of Piers' borane, [HAl(C6F5)(2)](3)1, is prepared on a gram-scale. Density functional theory (DFT) calculations reveal 1 has a higher fluoride ion affinity (FIA) than Piers' borane, while the Al-H moiety proved to be a strong hydride donor, reacting with alcohol and terminal alkyne to give the corresponding dehydrogenative products 3 and 4. Hydroalumination product 5 was prepared via reaction of 1 with aldehyde. In addition, 1 catalyzes the hydrosilylation of alkynes and alkenes.
相关链接	[来源记录]
收录类别	SCI
语种	英语
重要成果	NI论文
学校署名	通讯
资助项目	Ningbo Natural Science Foundation[202003N4094] ; Ningbo University["421999362","422110973"] ; Ningbo Top Talent Project[215-432094250] ; National Natural Science Foundation of China["22271132","22101114"] ; Shenzhen Science and Technology Innovation Program[JCYJ20220530114806015] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000895755400001
出版者	ROYAL SOC CHEMISTRY
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：1
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/420810
专题	理学院_化学系深圳格拉布斯研究院
作者单位	1.Ningbo Univ, Inst Drug Discovery Technol, Ningbo 315211, Zhejiang, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 4.Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada
通讯作者单位	化学系; 深圳格拉布斯研究院; 南方科技大学
推荐引用方式 GB/T 7714	Tan, Jingjie,Hu, Chaopeng,Yang, Xin,et al. Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3)[J]. CHEMICAL COMMUNICATIONS,2023,59(3).
APA	Tan, Jingjie.,Hu, Chaopeng.,Yang, Xin.,Ju, Shaoying.,Cao, Levy L..,...&Stephan, Douglas W..(2023).Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3).CHEMICAL COMMUNICATIONS,59(3).
MLA	Tan, Jingjie,et al."Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3)".CHEMICAL COMMUNICATIONS 59.3(2023).