南方科技大学知识苑(SUSTech KC): Catalyst-Controlled Product Selectivity for Cycloaddition of Bis(indol-3-yl)-allenes to Fused Spiroindolines and Mechanistic Studies

题名	Catalyst-Controlled Product Selectivity for Cycloaddition of Bis(indol-3-yl)-allenes to Fused Spiroindolines and Mechanistic Studies
作者	Zhang, Yan-Yan 1; Wei, Yin 1; Shi, Min1,2
通讯作者	Wei, Yin; Shi, Min
发表日期	2019-10-18
DOI	10.1021/acs.orglett.9b02992
发表期刊	ORGANIC LETTERS 影响因子和分区
ISSN	1523-7060
EISSN	1523-7052
卷号	21 期号:20页码:8250-8255
摘要	A catalyst-controlled cycloaddition reaction of bis(indol-3-yl)-allenes gives rise to two different types of fused spiroindolines hearing a spiro quaternary stereocenter, affording a range of fused spiroindolines in good yields. The asymmetric desymmetrization of bis(indol-3-yl)-allenes with very high regioselectivities and excellent enantioselectivities has been successfully established and catalyzed by (R)-DTBM-Segphos(AuNTf2)(2). Mechanistic studies through control experiments and DFT calculations provide plausible mechanistic proposals.
相关链接	[来源记录]
收录类别	SCI ; IC
语种	英语
重要成果	NI期刊
学校署名	通讯
资助项目	National Natural Science Foundation of China[20472096] ; National Natural Science Foundation of China[21372241] ; National Natural Science Foundation of China[21572052] ; National Natural Science Foundation of China[20672127] ; National Natural Science Foundation of China[21421091] ; National Natural Science Foundation of China[21372250] ; National Natural Science Foundation of China[21121062] ; National Natural Science Foundation of China[21302203] ; National Natural Science Foundation of China[21772226] ; National Natural Science Foundation of China[20732008] ; National Natural Science Foundation of China[21772037] ; National Natural Science Foundation of China[21861132014]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000492114600023
出版者	AMER CHEMICAL SOC
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：17
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/42119
专题	深圳格拉布斯研究院
作者单位	1.Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518000, Guangdong, Peoples R China
通讯作者单位	深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Zhang, Yan-Yan,Wei, Yin,Shi, Min. Catalyst-Controlled Product Selectivity for Cycloaddition of Bis(indol-3-yl)-allenes to Fused Spiroindolines and Mechanistic Studies[J]. ORGANIC LETTERS,2019,21(20):8250-8255.
APA	Zhang, Yan-Yan,Wei, Yin,&Shi, Min.(2019).Catalyst-Controlled Product Selectivity for Cycloaddition of Bis(indol-3-yl)-allenes to Fused Spiroindolines and Mechanistic Studies.ORGANIC LETTERS,21(20),8250-8255.
MLA	Zhang, Yan-Yan,et al."Catalyst-Controlled Product Selectivity for Cycloaddition of Bis(indol-3-yl)-allenes to Fused Spiroindolines and Mechanistic Studies".ORGANIC LETTERS 21.20(2019):8250-8255.