南方科技大学知识苑(SUSTech KC): Homogeneous Dearomative Hydrogenation with a Co/P4N2 Catalyst: A Nucleophilic Approach

题名	Homogeneous Dearomative Hydrogenation with a Co/P4N2 Catalyst: A Nucleophilic Approach
作者	Zhang, Shaoke1 ; Zhou, Rong1 ; Duan, Ya-Nan 2; Zhou, Yang1 ; Zhang, Xumu1 ; Wen, Jialin1
通讯作者	Zhang, Xumu; Wen, Jialin
发表日期	2022-12-01
DOI	10.1002/chem.202203189
发表期刊	CHEMISTRY-A EUROPEAN JOURNAL 影响因子和分区
ISSN	0947-6539
EISSN	1521-3765
卷号	29
摘要	Arene hydrogenation is the most straightforward method to prepare carbo- and heterocycles. However, the high resonance energy prevents aromatic substrates from hydrogenation. Herein the homogeneous, nucleophilic hydrogenation of less electron-rich arenes and heteroarenes is reported. The Co(P4N2)H species that has been demonstrated to be a strong hydride donor could deliver a hydride ion to the cyano (hetero)arene substrates. Deuterium labeling experiments supported a Michael-type reaction pathway. Theoretical analyses have been conducted to investigate the hydricity of the catalytically active CoH species and the electrophilicity of the arene substrates. An outlook for the synthesis of more challenging substituted benzenes was proposed based on the in silico modification of the CoH species.
关键词	hydrogenation cobalt dearomatization hydricity hydride transfer
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	第一 ; 通讯
资助项目	Chemistry and Chemical Engineering Guangdong Laboratory["2132013","2011006"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; China Postdoctoral Science Foundation[2020M672690]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000902954400001
出版者	WILEY-V C H VERLAG GMBH
EI入藏号	20225213308414
EI主题词	Aromatic hydrocarbons ; Aromatization ; Cobalt compounds ; Hydrides
EI分类号	Chemical Reactions:802.2 ; Organic Compounds:804.1 ; Inorganic Compounds:804.2
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：1
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/424877
专题	理学院_化学系
作者单位	1.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, 1088 Xueyuan Rd, Shenzhen 518055, Peoples R China 2.Chem & Chem Engn Guangdong Lab, Shantou 515031, Peoples R China
第一作者单位	化学系
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Zhang, Shaoke,Zhou, Rong,Duan, Ya-Nan,et al. Homogeneous Dearomative Hydrogenation with a Co/P4N2 Catalyst: A Nucleophilic Approach[J]. CHEMISTRY-A EUROPEAN JOURNAL,2022,29.
APA	Zhang, Shaoke,Zhou, Rong,Duan, Ya-Nan,Zhou, Yang,Zhang, Xumu,&Wen, Jialin.(2022).Homogeneous Dearomative Hydrogenation with a Co/P4N2 Catalyst: A Nucleophilic Approach.CHEMISTRY-A EUROPEAN JOURNAL,29.
MLA	Zhang, Shaoke,et al."Homogeneous Dearomative Hydrogenation with a Co/P4N2 Catalyst: A Nucleophilic Approach".CHEMISTRY-A EUROPEAN JOURNAL 29(2022).