Highly Regio- And Stereoselective Tridentate NCNN Cobalt-Catalyzed 1,3-Diyne Hydrosilylation

Kong，Degong1; Hu，Bowen1; Yang，Min1; Chen，Dafa1; Xia，Haiping2

2019

10.1021/acs.organomet.9b00602

ORGANOMETALLICS   影响因子和分区

0276-7333

1520-6041

A highly regio- and stereoselective tridentate NNN cobalt-catalyzed hydrosilylation of 1,3-diynes was developed. A wide range of 1,3-diynes was suitable for such transformations at room temperature, affording the corresponding silyl-functionalized 1,3-enynes in good yields within 5 min. These reactions can be readily scaled up to gram scale under mild conditions. To date, this is the most efficient cobalt catalytic system for the hydrosilylation of 1,3-diynes.

SCI ; EI ; IC ; CCR

英语

其他

National Natural Science Foundation of Heilongjiang[B2018005] ; National Natural Science Foundation of Heilongjiang[LC2018005]

Chemistry

Chemistry, Inorganic & Nuclear ; Chemistry, Organic

WOS:000496344400031

AMER CHEMICAL SOC

20194507634984

Catalysis ; Cobalt ; Stereoselectivity

Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Chemical Reactions:802.2

CHEMISTRY

2-s2.0-85074473069

Scopus

1.MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and StorageSchool of Chemical Engineering and TechnologyHarbin Institute of Technology,Harbin,150001,China
2.Shenzhen Grubbs InstituteDepartment of ChemistrySouthern University of Science and Technology,Shenzhen,China

Kong，Degong,Hu，Bowen,Yang，Min,et al. Highly Regio- And Stereoselective Tridentate NCNN Cobalt-Catalyzed 1,3-Diyne Hydrosilylation[J]. ORGANOMETALLICS,2019,38(21):4341-4350.

Kong，Degong,Hu，Bowen,Yang，Min,Chen，Dafa,&Xia，Haiping.(2019).Highly Regio- And Stereoselective Tridentate NCNN Cobalt-Catalyzed 1,3-Diyne Hydrosilylation.ORGANOMETALLICS,38(21),4341-4350.

Kong，Degong,et al."Highly Regio- And Stereoselective Tridentate NCNN Cobalt-Catalyzed 1,3-Diyne Hydrosilylation".ORGANOMETALLICS 38.21(2019):4341-4350.