| 题名 | Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(ii) complexes |
| 作者 | |
| 通讯作者 | Ye，Qing |
| 发表日期 | 2019
|
| DOI | |
| 发表期刊 | |
| ISSN | 1477-9226
|
| EISSN | 1477-9234
|
| 卷号 | 48期号:40页码:14962-14965 |
| 摘要 | The mononuclear cyclic (alkyl)(amino)carbene (cAAC) supported titanium(iii) chloride complex [(cAAC)TiCl] has been synthesized by treatment of free cAAC with TiCl(THF). Further reduction of (cAAC)TiCl with potassium graphite (KC) afforded the desired (cAAC)TiCl complex, which features a small S-T energy gap. Both complexes were structurally characterized and represent the first cAAC supported Ti complexes. |
| 相关链接 | [Scopus记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 第一
; 通讯
|
| 资助项目 | National Science Foundation[CHE-1566538]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Inorganic & Nuclear
|
| WOS记录号 | WOS:000498919700003
|
| 出版者 | |
| EI入藏号 | 20194307562223
|
| EI主题词 | Chlorine Compounds
; Organic Compounds
; Synthesis (Chemical)
|
| EI分类号 | Chemical Reactions:802.2
; Organic Compounds:804.1
|
| ESI学科分类 | CHEMISTRY
|
| Scopus记录号 | 2-s2.0-85073182744
|
| 来源库 | Scopus
|
| 引用统计 |
被引频次[WOS]：8
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/44056 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Department of ChemistrySouthern University of Science and Technology,Shenzhen Guangdong,518055,China 2.Department of ChemistryHong Kong University of Science and Technology,Kowloon,Clear Water Bay,Hong Kong 3.Department of ChemistryUniversity of CaliforniaBerkeley,Berkeley,94720-1460,United States 4.School of Chemistry and Chemical EngineeringSoutheast University,Nanjing,210089,China |
| 第一作者单位 | 化学系 |
| 通讯作者单位 | 化学系 |
| 第一作者的第一单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Ma，Wangyang,Zhang，Jing Xuan,Lin，Zhenyang,et al. Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(ii) complexes[J]. DALTON TRANSACTIONS,2019,48(40):14962-14965.
|
| APA |
Ma，Wangyang,Zhang，Jing Xuan,Lin，Zhenyang,Don Tilley，T.,&Ye，Qing.(2019).Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(ii) complexes.DALTON TRANSACTIONS,48(40),14962-14965.
|
| MLA |
Ma，Wangyang,et al."Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(ii) complexes".DALTON TRANSACTIONS 48.40(2019):14962-14965.
|
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| Dalton Transactions.（835KB） | -- | -- | 限制开放 | -- | ||
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