Reduced Fe, Mn-based catalyst with dual reaction sites for rapid decolorization treatment via Fenton-like reactions

Su，Yiping1,2; Long，Yangke2; Zhao，Shiyin2; Wang，Pengju2; Xie，Feng2; Huang，Junyi2; Han，Bing3; Zhang，Zuotai2; Zhang，Bo Ping1

2023-04-15

10.1016/j.apsusc.2023.156522

APPLIED SURFACE SCIENCE   影响因子和分区

0169-4332

1873-5584

Ferromanganese oxides are promising efficient catalysts for peroxymonosulfate (PMS) activation. In this study, a novel porous ferromanganese oxides (FeMnO) nanocubes derived from prussian blue analogues was prepared via a successive codeposition-calcination method, and the reduced Fe, Mn-based catalysts were further synthesized by a hydrogenation process. Their catalytic performance was evaluated in a Fenton-like degradation of Rhodamine B (RhB) and other dyes in the presence of PMS. It was found that FeMnO showed outstanding catalytic activity in dyes elimination, which benefited by the synergetic effect of dual reaction sites, reductive Fe-Mn binary oxides and oxygen vacancies (OVs) for PMS activation. The optimized sample (H annealed at 260 °C, FMO-260) exhibited high degradation efficiency to RhB within 5 cycles and after regeneration, implying the strong stability and reusability. Moreover, the influences of PMS and FMO-260 dosages, pH values, coexist anions for the degradation efficiency to RhB were also carried out. According to inhibitor experiments and EPR (electron paramagnetic resonance) tests, a possible catalytic mechanism and degradation pathway of RhB was proposed. This study provides a novel fabrication strategy to design Fe, Mn-based catalysts and demonstrates more potential in the decolorization field.

Decolorization Ferromanganese oxides Hydrogenation Oxygen vacancies Peroxymonosulfate

SCI ; EI

英语

通讯

National Science Fund for Distin- guished Young Scholars[52225407] ; Shenzhen Science and Tech- nology Innovation Committee["JCYJ20200109141437586","KCXFZ20211020174805008"] ; Shenzhen Peacock Plan[KQTD20160226195840229]

Chemistry ; Materials Science ; Physics

Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter

WOS:000934890700001

ELSEVIER

20230613539332

Binary alloys ; Catalysis ; Chemical activation ; Degradation ; Efficiency ; Electron spin resonance spectroscopy ; Hydrogenation ; Iron alloys ; Magnetite ; Oxidation ; Paramagnetic resonance ; Reusability ; Rhodium compounds

Iron Alloys:545.2 ; Magnetism: Basic Concepts and Phenomena:701.2 ; Chemistry:801 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Production Engineering:913.1

MATERIALS SCIENCE

2-s2.0-85147192296

Scopus

1.The Beijing Municipal Key Laboratory of New Energy Materials and Technologies,School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing,100083,China
2.School of Environmental Science and Engineering,Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
3.Department of Materials Science and Engineering,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China

Su，Yiping,Long，Yangke,Zhao，Shiyin,et al. Reduced Fe, Mn-based catalyst with dual reaction sites for rapid decolorization treatment via Fenton-like reactions[J]. APPLIED SURFACE SCIENCE,2023,616.

Su，Yiping.,Long，Yangke.,Zhao，Shiyin.,Wang，Pengju.,Xie，Feng.,...&Zhang，Bo Ping.(2023).Reduced Fe, Mn-based catalyst with dual reaction sites for rapid decolorization treatment via Fenton-like reactions.APPLIED SURFACE SCIENCE,616.

Su，Yiping,et al."Reduced Fe, Mn-based catalyst with dual reaction sites for rapid decolorization treatment via Fenton-like reactions".APPLIED SURFACE SCIENCE 616(2023).